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Walton, Paul
University of York
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2019Discovery, activity and characterisation of an AA10 lytic polysaccharide oxygenase from the shipworm symbiont <i>Teredinibacter turnerae</i>.citations
- 2011Insights into the oxidative degradation of cellulose by a copper metalloenzyme that exploits biomass componentscitations
- 2000Syntheses and structures of a range of metal complexes with the cis,cis-1,3,5-(E,E)-tris(phenylpropenylideneamino)cyclohexane
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article
Syntheses and structures of a range of metal complexes with the cis,cis-1,3,5-(E,E)-tris(phenylpropenylideneamino)cyclohexane
Abstract
<p>The ligand cis,cis-1,3,5-(E,E)-tris(phenylpropenylideneamino)cyclohexane (Ph-protach) was coordinated with a range of metal salts. The products were characterised by IR and H-1 NMR spectroscopies and FAB + MS. In addition, the complexes [Cu(Ph-protach)(eta(2)-SO4)][Cu(Ph-protach)(eta(1)-SO4)(CH3OH)], [Ni(Ph-protach)(Cl)]BPh4, [Zn(Ph-protach)(Cl)]BPh4 and [Cd(Ph-protach)(NO3)(CH3OH)]BPh4 were structurally analysed by single crystal X-ray diffraction. Each complex exhibits an N-3 face-capping coordination geometry around the metal ion and a stereochemically-rigid hydrophobic cavity around the metal ion's remaining coordination site(s).</p>