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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Minty, Ross F.
University of Strathclyde
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023The dependence of interfacial shear strength on temperature and matrix chemistry in glass fibre epoxy compositescitations
- 2022The influence of temperature and matrix chemistry on interfacial shear strength in glass fibre epoxy composites
- 2018Are silanes the primary driver of interface strength in glass fibre composites?
- 2018The influence of hardener-to-epoxy ratio on the interfacial strength in glass fibre reinforced epoxy compositescitations
- 2018Are silanes the primary driver of interface strength in glass fiber composites? An exploration of the relationship of chemical and physical parameters in the micromechanical characterisation of the apparent interfacial strength in glass fiber composites
- 2016The role of the epoxy resin
- 2015The role of the epoxy resin
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document
Are silanes the primary driver of interface strength in glass fiber composites? An exploration of the relationship of chemical and physical parameters in the micromechanical characterisation of the apparent interfacial strength in glass fiber composites
Abstract
It is probably not an overstatement to say that organosilanes are the most important class of chemicals used in the glass fiber, and consequently the composites, industry. One of the best-known assertions about these multifunctional silane molecules is that they promote chemical bonding across the fiber-matrix interface. However, the development of (non-reactive) thermoplastic matrix composites raises questions about the simplistic chemical bridging model of silanes at the interface. Moreover, despite the high level of attention commonly focused on the chemical influences on interfacial adhesion, a growing number of researchers have also commented on the role of residual stress contributing to the stress transfer capability at the fiber-matrix interface. We will review data on the temperature dependence of the apparent interfacial shear strength (IFSS) in (unsized) glass fiber-polypropylene, a system where there is no a priori reasoning to expect any chemical bonding at the interface. The results indicate that the apparent IFSS in thermoplastic composites can be largely explained by the residual thermal stresses. This phenomenon is characterised by a large drop in the measured IFSS when the test temperature is raised above the matrix Tg. We will also present data to show that the same phenomenon is present in the IFSS of glass fiber-epoxy composites, although the magnitude of the measured values of IFSS for epoxy systems cannot be explained by residual thermal stress alone. However, by further considering the possible contribution of the thermoset phenomenon of cure shrinkage we will demonstrate that it is also possible to explain the level of IFSS in this chemically reactive system by physical residual stresses alone. The state of the interface/interphase in epoxy systems is somewhat more complex than for (relatively) non-reactive thermoplastics. This presentation will review our results on the investigation of this complex experimental challenge. Many of the properties required in the modelling of residual ...