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Torkelson, John M.
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Topics
Publications (14/14 displayed)
- 2022Functional enzyme–polymer complexescitations
- 2011Effect of gradient sequencing on copolymer order-disorder transitionscitations
- 2009Melt rheology and x-ray analysis of gradient copolymers
- 2009Glass transition breadths and composition profiles of weakly, moderately, and strongly segregating gradient copolymerscitations
- 2008Microphase separation and shear alignment of gradient copolymerscitations
- 2006Confinement, composition, and spin-coating effects on the glass transition and stress relaxation of thin films of polystyrene and styrene-containing random copolymerscitations
- 2005Impacts of polystyrene molecular weight and modification to the repeat unit structure on the glass transition-nanoconfinement effect and the cooperativity length scalecitations
- 2005On the glass transition and physical aging in nanoconfined polymers
- 2004Erratumcitations
- 2004Effects of free-surface and interfacial layers and plasticizer content on the distribution of glass transition temperatures in nanoconfined polymers
- 2004Dramatic reduction of the effect of nanoconfinement on the glass transition of polymer films via addition of small-molecule diluentcitations
- 2004In situ monitoring of sorption and drying of polymer films and coatingscitations
- 2003The distribution of glass-transition temperatures in nanoscopically confined glass formerscitations
- 2002Sensing the glass transition in thin and ultrathin polymer films via fluorescence probes and labelscitations
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document
Melt rheology and x-ray analysis of gradient copolymers
Abstract
<p>Gradient copolymers have great versatility in terms of sequence distribution of monomers along the polymer backbone for control over their level of nanophase heterogeneity and flow properties. Using a gradient composition rather than a block-type distribution, it is possible to design longer chains which undergo nanophase segregation at lower temperatures yet become more homogeneous and melt processible at accessible temperatures. These behaviors are investigated for a range of block and gradient architectures using melt rheology and small-angle x-ray scattering.</p>