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Burghardt, Wesley R.
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Publications (7/7 displayed)
- 2009Melt rheology and x-ray analysis of gradient copolymers
- 2008Microphase separation and shear alignment of gradient copolymerscitations
- 2007Shear flow behavior of a dynamically symmetric polymeric bicontinuous microemulsioncitations
- 2002Linear viscoelasticity of a polymeric bicontinuous microemulsioncitations
- 2002Thermoreversible, Epitaxial [Formula presented] Transitions in Block Copolymer Solutionscitations
- 2002Time-resolved small-angle x-ray scattering measurements of a polymer bicontinuous microemulsion structure factor under shearcitations
- 2002Effects of shear flow on a polymeric bicontinuous microemulsioncitations
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document
Melt rheology and x-ray analysis of gradient copolymers
Abstract
<p>Gradient copolymers have great versatility in terms of sequence distribution of monomers along the polymer backbone for control over their level of nanophase heterogeneity and flow properties. Using a gradient composition rather than a block-type distribution, it is possible to design longer chains which undergo nanophase segregation at lower temperatures yet become more homogeneous and melt processible at accessible temperatures. These behaviors are investigated for a range of block and gradient architectures using melt rheology and small-angle x-ray scattering.</p>