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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mishra, S.
Max Planck Institute for Chemical Physics of Solids
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2024Precursor-employed sol-gel synthesis of mesostructured fluorinated titania for acid catalysis
- 2023Single-track thermal analysis of laser powder bed fusion process: Parametric solution through physics-informed neural networkscitations
- 2023Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Aucitations
- 2023In situ X-ray diffraction study of a TiO2 nanopowder Spark Plasma Sintering under very high pressurecitations
- 2023In situ X-ray diffraction study of a TiO2 nanopowder Spark Plasma Sintering under very high pressurecitations
- 2023The Lorenz ratio as a guide to scattering contributions to Planckian transport
- 2023A spatially resolved optical method to measure thermal diffusivitycitations
- 2023Steering Large Magnetic Exchange Coupling in Nanographenes near the Closed-Shell to Open-Shell Transitioncitations
- 2020Precursor Mediated Synthesis of Binary and Ternary Metal Chalcogenide Nanoparticles for Photocatalytic Applications
- 2020Tailoring Vanadium Dioxide Film Orientation Using Nanosheets:A Combined Microscopy, Diffraction, Transport, and Soft X-Ray in Transmission Studycitations
- 2020Quest to enhance up-conversion efficiency: a comparison of anhydrous vs. hydrous synthesis of NaGdF4: Yb3+ and Tm3+ nanoparticlescitations
- 2019Facile precursor-mediated synthesis of binary and ternary G11 metal selenide-based nanomaterials for improved photocatalysis
- 2019Sol-gel preparation of doped-metal oxide nanostructures for the thermoelectric conversion of energy
- 2019Sol-gel preparation of doped-metal oxide nanostructures for the thermoelectric conversion of energy
- 2019Precursor-directed synthesis of upconverting LiYF4:Yb3+, Tm3+ nanoparticles and their composites designed for near infra-red driven photocatalysis
- 2019Synthesis of Binary and Ternary Metal Selenide Nanoparticles for Photocatalytic Applications: A Study of Molecule-to-Nanoparticles Transformation Mechanism
- 2018A precursor-directed synthesis of Cu2-xSe nanoparticles and its composites with TiO2 for enhanced photocatalytic activity
- 2018A precursor-directed synthesis of inorganic nanomaterials for photocatalytic applications
- 2017Oxide Thermoelectrics Nanostructured by Spinodal Decomposition
- 2017Oxide Thermoelectrics Nanostructured by Spinodal Decomposition
- 2017Development of intra- and inter-granular nanometric architectures in metal oxides for the thermoelectric conversion of energy.
- 2017Development of intra- and inter-granular nanometric architectures in metal oxides for the thermoelectric conversion of energy.
- 2017Development of thermoelectric metal oxides : the case of doped TiO2
- 2017Development of thermoelectric metal oxides : the case of doped TiO2
- 2017Tensile and flexural properties of hybrid graphene oxide/epoxy carbon fibre reinforced composites.citations
- 2016divergent reactivity of selenoethers with metal reagents: formation of molecular complexes vs. metal selenide nanoparticles
- 2016A Facile Molecular Precursor-based Synthesis of Ag2Se Nanoparticles and Its Composites with TiO2 for Enhanced Photocatalytic Activitycitations
- 2016asymmetric ligand approach to design volatile molecular precursors for the al-fe intermetallic catalyst
- 2014Single source precursors for heterometallic fluoride nanomaterials
- 2012Novel heterometal-organic complexes as first single source precursors for up-converting NaY(Ln)F-4 (Ln = Yb, Er, Tm) nanomaterialscitations
- 2012Heterometallic, Hybrid, Heavy Main-Group Iodometallates Containing Lanthanide Complexes: Template Synthesis, Structures, Thermal, Optical, Luminescent and Magnetic Propertiescitations
- 2010Dimethyl selenide complexes of copper, gallium and indium halides as potential precursors for selenium-containing chalcopyrite semiconducting materialscitations
- 2009Homoleptic gallium(III) and indium(III) aminoalkoxides as precursors for sol-gel routes to metal oxide nanomaterialscitations
- 2005Plant fibers as reinforcement for green composites
Places of action
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document
Oxide Thermoelectrics Nanostructured by Spinodal Decomposition
Abstract
High-efficiency thermoelectric (TE) materials are important for power-generation devices that are designed to convert waste heat into electrical energy or to use in solid-state refrigeration. These applications require innovative materials which not only possess high conversion efficiency (related to high dimensionless number called figure of merit, "ZT" which is a combination of three material properties: Seebeck coefficient, electrical conductivity and thermal conductivity , but should also be no toxic and have high chemical stability in air, over a wide temperature range such as oxide materials. From last decade, a major breakthrough in the field of TE came by designing nanostructures that scatter phonons more effectively than electrons, so that the thermal conductivity is reduced more than the electrical conductivity. Herein we present a cheap and thermodynamically driven process to produce intra-granular nanostructures in bulk materials: the spinodal decomposition in the Nb5+-doped SnO2-TiO2 system via an innovative molecular approach. Such in-situ partitioning takes advantage to produce nanostructuration with coherent interfaces. While classical approach based on SnO2 (nano)powders mixing faces trouble to sinter dense ceramics, our bottom-up approach, trough synthesis of mixed TixSn1-xO2 (x = 0.25; 0.5; 0.75) rutile nanoparticles, suppress pure SnO2 grains and allow full densification at low temperature by SPS process. Impact of the pressure, heating rate and soaking time of SPS process onto the densification, the nano-structuration and the dopant distribution will be addressed towards the thermoelectric properties.