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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rossi, Emanuele
ETH Zurich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Chloride-induced corrosion of steel in concrete—insights from bimodal neutron and X-ray microtomography combined with ex-situ microscopycitations
- 2024Chloride-induced corrosion of steel in concrete—insights from bimodal neutron and X-ray microtomography combined with ex-situ microscopycitations
- 2022Influence of self-healing induced by polylactic-acid and alkanoates-derivates precursors on transport properties and chloride penetration resistance of sound and cracked mortar specimenscitations
- 2021Freeze-thaw resistance and air-void analysis of concrete with recycled glass-pozzolan using X-ray micro-tomographycitations
- 2021A study of the elastic moduli and chemical composition of corrosion product naturally-generated due to chlorides through nano-indentation and energy dispersive X-ray spectrometry (EDS)
- 2021Analysis of naturally-generated corrosion products due to chlorides in 20-year old reinforced concretecitations
- 2021Assessment of the self-healing capacity of cementitious materials through active thin sectionscitations
- 2021Accelerated carbonation of ordinary Portland cement paste and its effects on microstructure and transport properties
- 2021Assessment of freeze-thaw resistance of cement based concrete with ground glass – pozzolan through X-ray microtomography
- 2020The influence of defects at the steel/concrete interface for chloride-induced pitting corrosion of naturally-deteriorated 20-years-old specimens studied through X-ray Computed Tomographycitations
- 2020Encapsulation Techniques and Test Methods of Evaluating the Bacteria-Based Self-Healing Efficiency of Concrete : A Literature Reviewcitations
- 2019On The Role Of Soft Inclusions On The Fracture Behaviour Of Cement Pastecitations
- 2019The influence of defects at the steel/concrete interface for pitting corrosion initiation studied through X-ray Computed Tomography and image analysiscitations
Places of action
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document
A study of the elastic moduli and chemical composition of corrosion product naturally-generated due to chlorides through nano-indentation and energy dispersive X-ray spectrometry (EDS)
Abstract
An important input parameter for numerical models that simulate cracking of the concrete cover due to reinforcement corrosion is the Elastic modulus of corrosion product (Ecp). Despite its relevance, Ecp is subject of significant variations according to the values reported in the literature, which vary from less than 100 MPa up to 360 GPa. Furthermore, Ecp values proposed in most of the present literature are representative of the corrosion product generated by anodic accelerated corrosion or extracted from the steel/concrete interface (SCI), which might differ from that formed in real corroding structures. Therefore, this study aims to investigate the Elastic modulus of naturally-generated corrosion product present at the SCI through nano-indentation conducted on six reinforced concrete polished sections. The polished sections were obtained from six 20-year-old reinforced concrete prisms cast with different cement type (CEM I, CEM II/B-V, CEM III/B, CEM V/A), same water/binder ratio (0.55) and which were previously exposed to NaCl solution wet/dry cycles. This study revealed that the range of Ecp did not considerably vary between corrosion products formed in different concrete mixes. However, corrosion product was microscopically found to consist of overlapping bands with different Ecp, varying for up to around 70 GPa between each other. Through Environmental Scanning-Electron Microscopy (ESEM) and Energy Dispersive Xray Spectrometry (EDS) analysis of the indented locations, it was found that Ecp is highly dependent on the presence of interfacial cracks and inversely proportional to the concentration of Si and Ca, representative for corrosion product mixed with the surrounding concrete. Furthermore, higher concentration of Fe leads to higher Ecp. Based on this study, an average range of values for Ecp between 80-100 GPa can be suggested for use in numerical models for corrosion induced cracking, regardless of cement type of the structure under investigation.