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| Naji, M. |
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Dehmel, Raphael
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Topics
Publications (5/5 displayed)
- 2019Metasurfaces Atop Metamaterials: Surface Morphology Induces Linear Dichroism in Gyroid Optical Metamaterials.
- 2018Controlling Self-Assembly in Gyroid Terpolymer Films By Solvent Vapor Annealing.
- 2018Controlling Self-Assembly in Gyroid Terpolymer Films By Solvent Vapor Annealing.
- 2017Optical Imaging of Large Gyroid Grains in Block Copolymer Templates by Confined Crystallization.
- 20153D Nanostructured Conjugated Polymers for Optical Applications
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document
3D Nanostructured Conjugated Polymers for Optical Applications
Abstract
This is the final version of the article. It first appeared from Wiley via http://dx.doi.org/10.1002/adfm.201502392 ; <jats:p>The self assembly of block‐copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4‐ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self‐assembled morphology into self‐supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.</jats:p> ; We acknowledge the EPSRC EP/G060649/1 for funding. This study was supported by the Nokia Research Centre Cambridge.