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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sukackienė, Zita
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024The Dependence of NiMo/Cu Catalyst Composition on Its Catalytic Activity in Sodium Borohydride Hydrolysis Reactionscitations
- 2024Hydrogen and Oxygen Evolution on Flexible Catalysts Based on Nickel–Iron Coatings
- 2024Electrolessly Deposited Cobalt–Phosphorus Coatings for Efficient Hydrogen and Oxygen Evolution Reactions
- 2023Hydrogen production on CoFe, CoFeMn and CoFeMo coatings deposited on Ni foam via electroless metal platingcitations
- 2023Non-Precious Metals Catalysts for Hydrogen Generationcitations
- 2022Comparison of the Activity of 3D Binary or Ternary Cobalt Coatings for Hydrogen and Oxygen Evolution Reactionscitations
- 2020Investigation of Glucose Oxidation on Gold Nanocrystallites Modified Cobalt and Cobalt-Boron Coatings
- 2020Bimetallic Co-Based (CoM, M = Mo, Fe, Mn) Coatings for High-Efficiency Water Splittingcitations
- 2019Investigation of glucose electro-oxidation on Co and CoB alloy coatings modified with Au nanoparticlescitations
- 2018Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
- 2016Electroless Deposition of Cobalt-Tungsten-Boron Films from Glycine Containing Solutions As Barrier Layer Against Cu Diffusion
- 2014Electroless Co-B-P-W Deposition Using DMAB as Reducing Agent
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article
Hydrogen production on CoFe, CoFeMn and CoFeMo coatings deposited on Ni foam via electroless metal plating
Abstract
<jats:p>
 
 
 
 In this study, the catalytic hydrogen generation was evaluated on the cobalt–iron (CoFe), cobalt–iron–manganese (CoFeMn) and cobalt–ironmolybdenum (CoFeMo) coatings deposited on the Ni foam substrate using the electroless metal plating method and morpholine borane as the reducing agent. The characterisation of the surface morphology, structure and composition of resulted coatings was done using scanning electron microscopy (SEM) and inductively coupled plasma optical emission spectroscopy (ICP-OES). The catalytic activity of the prepared CoFe/Ni, CoFeMn/Ni and CoFeMo/Ni catalysts was investigated for hydrogen generation from an alkaline sodium borohydride (NaBH4) solution at different temperatures. It was found that the hydrogen generation rate of ca. 5.2, 7.8 and 11.7 L min–1 g–1 was achieved by using the CoFe/ Ni, CoFeMo/Ni and CoFeMn/Ni coatings, respectively, at 343 K. Among the investigated catalysts, CoFeMn/Ni exhibits the lowest activation energy of 62.4 kJ mol–1 and the highest HGR of 11.7 L min–1 g–1 at 343 K.
 
 
 
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