| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Picchioni, Francesco
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (48/48 displayed)
- 2024Phase inversion detection in immiscible binary polymer blends via zero-shear viscosity measurementscitations
- 2024Phase inversion detection in immiscible binary polymer blends via zero-shear viscosity measurementscitations
- 2024A novel SBS compound via blending with PS-B-PMBL diblock copolymer for enhanced mechanical propertiescitations
- 2023Electrically and thermally healable nanocomposites via one-step Diels-Alder reaction on carbon nanotubescitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Effect of Polymer Composition on the Optical Properties of a New Aggregation-Induced Emission Fluorophore: A Combined Experimental and Computational Approach
- 2023Effect of Polymer Composition on the Optical Properties of a New Aggregation-Induced Emission Fluorophore:A Combined Experimental and Computational Approach
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022RAFT Polymerization of a Biorenewable/Sustainable Monomer via a Green Processcitations
- 2022Rapid self-healing in IR-responsive plasmonic indium tin oxide/polyketone nanocompositescitations
- 2022Synthesis and solution properties of poly(p,α dimethylstyrene-co-maleic anhydride)citations
- 2022Rapid Self-Healing in IR-Responsive Plasmonic Indium Tin Oxide/Polyketone Nanocompositescitations
- 2022The Effect of Molecular Weight on the (Re)-Processability and Material Properties of Bio-Based, Thermoreversibly Cross-Linked Polyesterscitations
- 2021Polytriphenylamine composites for energy storage electrodes:Effect of pendant vs. backbone polymer architecture of the electroactive groupcitations
- 2021Thermally Switchable Electrically Conductive Thermoset rGO/PK Self-Healing Compositescitations
- 2021Thermally Switchable Electrically Conductive Thermoset rGO/PK Self-Healing Compositescitations
- 2021A Hierarchical Hybrid Method for Screening Ionic Liquid Solvents for Extractions Exemplified by the Extractive Desulfurization Processcitations
- 2021Self-Healing Polymer Nanocomposite Materials by Joule Effectcitations
- 2021Polytriphenylamine composites for energy storage electrodescitations
- 2020Mechanical properties and electrical surface charges of microfibrillated cellulose/imidazole-modified polyketone composite membranescitations
- 2020Mechanical properties and electrical surface charges of microfibrillated cellulose/imidazole-modified polyketone composite membranescitations
- 2020Highly Branched Waxy Potato Starch-Based Polyelectrolyte:Controlled Synthesis and the Influence of Chain Composition on Solution Rheologycitations
- 2020Highly Branched Waxy Potato Starch-Based Polyelectrolytecitations
- 2020Influence of the polymer properties and numerical schemes on tertiary oil recovery processescitations
- 2020The effect of macromolecular structure on the rheology and surface properties of amphiphilic random polystyrene-r-poly(meth)acrylate copolymers prepared by RDRPcitations
- 2020Implementation of the UNIQUAC model in the OpenCalphad softwarecitations
- 2019Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bondscitations
- 2019Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bondscitations
- 2019Influence of the polymer degradation on enhanced oil recovery processescitations
- 2019Thermoreversible Polymeric Nanocomposites
- 2019Luminescent Solar Concentrators Based on Renewable Polyester Matricescitations
- 2018Thermoreversibly cross-linked EPM rubber nanocomposites with carbon nanotubescitations
- 2018Effect of the Polyketone Aromatic Pendent Groups on the Electrical Conductivity of the Derived MWCNTs-Based Nanocompositescitations
- 2018Thermo-Responsive Starch-g-(PAM-co-PNIPAM):Controlled Synthesis and Effect of Molecular Components on Solution Rheologycitations
- 2018Starlike Branched Polyacrylamides by RAFT Polymerization-Part I:Synthesis and Characterizationcitations
- 2018Thermoreversibly Cross-Linked EPM Rubber Nanocomposites with Carbon Nanotubescitations
- 2018Electrically-responsive reversible Polyketone/MWCNT network through Diels-Alder chemistrycitations
- 2017Micromechanical assessment of PMMA microcapsules containing epoxy and mercaptan as self-healing agentscitations
- 2017Triblock copolymers of styrene and sodium methacrylate as smart materials:synthesis and rheological characterizationcitations
- 2010Extraction of Jatropha curcas proteins and application in polyketone-based wood adhesivescitations
- 2008Cross-linking of multiwalled carbon nanotubes with polymeric aminescitations
- 2007Batch production of micron size particles from poly(ethylene glycol) using supercritical CO2 as a processing solventcitations
- 2005Synthetic aspects and characterization of polypropylene-silica nanocomposites prepared via solid-state modification and sol-gel reactions
- 2002Blends of syndiotactic polystyrene with SEBS triblock copolymerscitations
- 2001Blends of syndiotactic polystyrene with SBS triblock copolymers
- 2000Controlled Functionalization of Olefin/styrene Copolymers through Free Radical Processes
Places of action
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article
A novel SBS compound via blending with PS-B-PMBL diblock copolymer for enhanced mechanical properties
Abstract
Styrene–butadiene–styrene (SBS) rubbers are one of the most frequently used thermoplastic elastomers globally. The upper operating temperature of SBS is limited by the glass transition temperature (T g ) of poly(styrene) (PS), circa 100°C. This study demonstrates a noteworthy enhancement in the properties of SBSs by introducing a diblock copolymer consisting of styrene and α-methylene-γ-butyrolactone (α-MBL). Polymers derived from α-MBL exhibit exceptional thermal stability, attributable to a T g of 195°C. Notably, α-MBL, also recognized as Tulipalin A, is a biorenewable compound naturally found in tulips. This investigation encompasses both crosslinked and noncrosslinked blends of poly(styrene)block-poly(α-methylene-γ-butyrolactone) diblock copolymer (PS-b-PMBL) and poly(styrene)-block-poly(butadiene)-block-poly(styrene) triblock copolymer, within the 0–20 wt% PS-b-PMBL range. Thorough examination using thermal analysis and linear shear rheology reveals that all blends surpass the properties of their pure SBS counterparts. Specifically, blending at 200°C induces crosslinking between the polymers, yielding heightened Young’s modulus and complex viscosity, thereby resulting in a robust and rigid material compared with noncrosslinked blends. For noncrosslinked blends, an increase in strength is observed while maintaining commendable rubbery properties. Notably, the noncrosslinked blends permit the recycling of components (SBS and PS-b-PMBL) through the redissolving of rubber in tetrahydrofuran. These findings present a promising avenue for the enhancement of rubbers through the incorporation of biorenewable compounds.