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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Morgen, Per
University of Southern Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Impact of drug compounds mechanical/deformation properties on the preparation of nano- and microsuspensionscitations
- 2024Impact of drug compounds mechanical/deformation properties on the preparation of nano- and microsuspensionscitations
- 2022Post-degradation case study of the membrane electrode assembly from a low-temperature PEMFC stack
- 2022Post-degradation case study of the membrane electrode assembly from a low-temperature PEMFC stack
- 2022En metode til at danne kobberlag på porøst aluminium oxid (PAO) på et substrat af aluminium legering ; A method for manufacturing copper film on porous aluminum oxide (pao) on an aluminum alloy substrate
- 2022Insights into Degradation of the Membrane–Electrode Assembly Performance in Low-Temperature PEMFC:the Catalyst, the Ionomer, or the Interface?citations
- 2022A method for manufacturing copper film on porous aluminum oxide (pao) on an aluminum alloy substrate
- 2022Insights into Degradation of the Membrane–Electrode Assembly Performance in Low-Temperature PEMFCcitations
- 2020Platinum recycling through electroless dissolution under mild conditions using a surface activation assisted Pt-complexing approachcitations
- 2020Platinum recycling through electroless dissolution under mild conditions using a surface activation assisted Pt-complexing approachcitations
- 2017Growth of aluminum oxide on silicon carbide with an atomically sharp interfacecitations
- 2016The effect of trace amounts of copper on the microstructure, stability and oxidation of macroporous silicon carbidecitations
- 2016The effect of trace amounts of copper on the microstructure, stability and oxidation of macroporous silicon carbidecitations
- 2016The role of aluminium as an additive element in the synthesis of porous 4H-silicon carbidecitations
- 2016The role of aluminium as an additive element in the synthesis of porous 4H-silicon carbidecitations
- 2015The role of Aluminium in the synthesis of Mesoporous 4H Silicon Carbide
- 2015The role of Aluminium in the synthesis of Mesoporous 4H Silicon Carbide
- 2013Investigations on sputter deposited LiCoO2 thin films from powder targetcitations
- 2009Self-activated, self-limiting reactions on Si surfaces
- 2006Epitaxial growth of Al on Si(1 1 1) with Cu buffer layerscitations
Places of action
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article
Investigations on sputter deposited LiCoO2 thin films from powder target
Abstract
<p>LiCoO<sub>2</sub> thin films used as cathode layers in thin-film solid-state batteries have been deposited from LiCoO<sub>2</sub> powder target using radio frequency (rf) magnetron sputtering in a cost effective approach in terms of material consumption and processing time. Xray diffraction (XRD) studies of the films after post deposition annealing treatment revealed (104) orientation, which is the characteristic of rf sputtered LiCoO<sub>2</sub> films. Raman spectroscopy was used to identify the different modes of vibration of atoms in the film. The surface morphology and cross-section of the samples were characterized using field emission scanning electron microscopy (SEM). The chemical analysis of LiCoO<sub>2</sub> thin films was examinedby X-ray photoelectron spectroscopy (XPS) showed atomic ratio of Li/Co as 0.9 which is close to the ideal value 1. Electrochemical characterization such as charge -discharge andcyclic voltammetry were conducted for LiCoO<sub>2</sub> films deposited on platinized silicon substrates in the potential range 3.0 to 4.2 V vs Li/Li<sup>+</sup>. The maximum discharge capacity of 64 μAh.μm<sup>-1</sup>. cm<sup>-2</sup> and 52 μAh. μm<sup>-1</sup>.cm<sup>-2</sup> were achieved when discharged at a current of 5 μAand 50 μA for the first discharge cycle respectively. Moreover the electrochemical investigations of LiCoO<sub>2</sub> thin films on flexible copper substrates also investigated and achieved an initial discharge capacity of 83 mAh/g. The possible reasons for degradation in the electrochemical properties have been discussed. The present work indicates suitability of sputtering from powder targets for thin film battery fabrication.</p>