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Publications (6/6 displayed)
- 2024Improved sequentially processed Cu(In,Ga)(S,Se)2 by Ag alloying
- 2024Improved Sequentially Processed Cu(In,Ga)(S,Se)<sub>2</sub> by Ag Alloying
- 2020Chemical instability at chalcogenide surfaces impacts chalcopyrite devices well beyond the surfacecitations
- 2018Synthesis, theoretical and experimental characterisation of thin film Cu2Sn1-xGexS3 ternary alloys (x = 0 to 1): Homogeneous intermixing of Sn and Gecitations
- 2018Synthesis, theoretical and experimental characterisation of thin film Cu2Sn1-Ge S3 ternary alloys (x = 0 to 1): homogeneous intermixing of Sn and Gecitations
- 2015Process variability in Cu2ZnSnSe4 solar cell devices: Electrical and structural investigationscitations
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article
Improved sequentially processed Cu(In,Ga)(S,Se)2 by Ag alloying
Abstract
Alloying small quantities of silver into Cu(In,Ga)Se2 was shown to improve the efficiency for wide and low band gap solar cells. We study low band gap industrial Cu(In,Ga)(S,Se)2 absorbers, substituting less than 10% of the copper with silver, using absolute photoluminescence and cathodoluminescence spectroscopy. Silver improves the grain size and promotes the interdiffusion of Ga and In across the depth of the absorber, resulting in a smoother band gap gradient. However, a certain lateral inhomogeneity is observed near the front and back sides. The non-radiative losses in the bare absorbers are reduced by up to 30 meV.