People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Maaß, Robert
John Wiley & Sons (Germany)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (31/31 displayed)
- 2024Microplastic response of 2PP‐printed ceramicscitations
- 2024Atomic cluster dynamics causes intermittent aging of metallic glassescitations
- 2024Giant segregation transition as origin of liquid metal embrittlement in the Fe-Zn systemcitations
- 2024Miniaturized bulk metallic glass gripping structures for robotic mobility platformscitations
- 2024Intermittent cluster dynamics and temporal fractional diffusion in a bulk metallic glasscitations
- 2024Small-scale functional fatigue of a Ni-Mn-Ga Heusler alloycitations
- 2023Insights into Plastic Localization by Crystallographic Slip from Emerging Experimental and Numerical Approachescitations
- 2023Giant segregation transition as origin of liquid metal embrittlement in the Fe-Zn system
- 2023nanoindentation data associated with the publication "On the elastic microstructure of bulk metallic glasses" in Materials&Design 2023
- 2023Constrained incipient phase transformation in Ni-Mn-Ga films: A small-scale design challengecitations
- 2023Growth Twins and Premartensite Microstructure in Epitaxial Ni-Mn-Ga Filmscitations
- 2023On the elastic microstructure of bulk metallic glassescitations
- 2023Entering a New Dimension in Powder Processing for Advanced Ceramics Shapingcitations
- 2023Segregation-induced grain-boundary precipitation during early stages of liquid-metal embrittlement of an advanced high-strength steelcitations
- 2023Silicate glass fracture surface energy calculated from crystal structure and bond-energy datacitations
- 2022In situ thermal annealing transmission electron microscopy of irradiation induced Fe nanoparticle precipitation in Fe–Si alloycitations
- 2022In situ thermal annealing transmission electron microscopy of irradiation induced Fe nanoparticle precipitation in Fe–Si alloycitations
- 2022Intermittent microplasticity in the presence of a complex microstructurecitations
- 2022Mild-to-wild plastic transition is governed by athermal screw dislocation slip in bcc Nbcitations
- 2022Spatially resolved roughness exponent in polymer fracturecitations
- 2022Optimally rejuvenated model binary glassescitations
- 2022Entering a new dimension in powder processing for advanced ceramics shapingcitations
- 2021Microstructural signatures of dislocation avalanches in a high-entropy alloycitations
- 2021Evidence of room-temperature shear-deformation in a Cu-Al intermetalliccitations
- 2021Early stages of liquid-metal embrittlement in an advanced high-strength steelcitations
- 2021Viscosity and transport in a model fragile metallic glasscitations
- 2021Microstructure and nanomechanical behavior of sputtered CuNb thin filmscitations
- 2021Strain-dependent shear-band structure in a Zr-based bulk metallic glasscitations
- 2021Micro-plasticity in a fragile model binary glasscitations
- 2020Structural dynamics and rejuvenation during cryogenic cycling in a Zr-based metallic glasscitations
- 2020Split-vacancy defect complexes of oxygen in hcp and fcc cobaltcitations
Places of action
Organizations | Location | People |
---|
article
Giant segregation transition as origin of liquid metal embrittlement in the Fe-Zn system
Abstract
A giant Zn segregation transition is revealed using CALPHAD-integrated density-based modelling of Zn segregation into Fe grain boundaries (GBs). The results show that above a threshold of only a few atomic percent Zn in the alloy, a substantial amount of up to 60 at.% Zn can segregate to the GB. We also found that the amount of segregation significantly increases with decreasing temperature, while the required Zn content in the alloy for triggering the segregation transition decreases. Direct evidence of this Zn segregation transition is obtained using high-resolution scanning transmission electron microscopy. We trace the origin of the segregation transition and its temperature dependence back to the low cohesive energy of Zn and a miscibility gap in Fe-Zn GB, arising from the magnetic ordering effect, which is demonstrated by ab initio calculations. We show that the massive Zn segregation resulting from the segregation transition greatly assists with liquid wetting and reduces the work of separation along the GB. These findings reveal the fundamental origin of GB weakening and therefore liquid metal embrittlement in the Fe-Zn system.