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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhou, Xuyang
Max-Planck-Institut für Eisenforschung
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Determination of five-parameter grain boundary characteristics in nanocrystalline Ni-W by Scanning Precession Electron Diffraction Tomography
- 2024Determination of five-parameter grain boundary characteristics in nanocrystalline Ni-W by scanning precession electron diffraction tomographycitations
- 2024Atom probe tomography-assisted kinetic assessment of spinodal decomposition in an Al-12.5 at.%Zn alloycitations
- 2024Correlating grain boundary character and composition in 3-dimensions using 4D-scanning precession electron diffraction and atom probe tomography
- 2023Interstitial Segregation has the Potential to Mitigate Liquid Metal Embrittlement in Ironcitations
- 2023Tailoring the Plasticity of Topologically Close‐packed Phases via the Crystals’ Fundamental Building Blockscitations
- 2023Constructing phase diagrams for defects by correlated atomic-scale characterizationcitations
- 2023Tailoring the Plasticity of Topologically Close‐Packed Phases via the Crystals’ Fundamental Building Blockscitations
- 2022Reconstructing dual-phase nanometer scale grains within a pearlitic steel tip in 3D through 4D-scanning precession electron diffraction tomography and automated crystal orientation mappingcitations
- 2022Elucidation of formation and transformation mechanisms of Ca-rich Laves phase in Mg-Al-Ca-Mn alloyscitations
- 2021Beyond Solid Solution High-Entropy Alloys: Tailoring Magnetic Properties via Spinodal Decompositioncitations
- 2020Laser shocking of nanocrystalline materials: Revealing the extreme pressure effects on the microstructural stability and deformation responsecitations
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document
Constructing phase diagrams for defects by correlated atomic-scale characterization
Abstract
Phase transformations and crystallographic defects are two essential tools to drive innovations in materials. Bulk materials design via tuning chemical compositions has been systematized using phase diagrams. We show here that the same thermodynamic concept can be applied to understand the chemistry at defects. We present a combined experimental and modelling approach to scope and build phase diagrams for defects. The discovery was enabled by triggering phase transformations of individual defects through local alloying, and sequentially imaging the structural and chemical changes using atomic-resolution scanning transmission electron microscopy. By observing atomic-scale phase transformations of a Mg grain boundary through Ga alloying, we exemplified the method to construct a grain boundary phase diagram using ab initio simulations and thermodynamic principles. The methodology enables a systematic development of defect phase diagrams to propel a new paradigm for materials design utilizing chemical complexity and phase transformations at defects.