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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Warad, Ismail
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Publications (7/7 displayed)
- 2024Anticorrosive characteristics of imidazole derivative on carbon steel in 1 M HClcitations
- 2024Inhibition performance of a novel quinoxaline derivative for carbon steel corrosion in 1 M HCl
- 2023Assessment of New Imidazol Derivatives and Investigation of Their Corrosion-Reducing Characteristics for Carbon Steel in HCl Acid Solutioncitations
- 2020Crystal interaction, XRD powder, and Hirshfeld surface analysis of S-benzyl-β-N-(1-(4-chlorophenyl) ethylidene) dithiocarbazate Schiff base
- 2017Steric repulsion and supramolecular assemblies via a two-dimensional plate by C—H...O hydrogen bonds in two closely related 2-(benzofuran-2-yl)-2-oxoethyl benzoates
- 2017Synthesis, solvatochromism and crystal structure of trans-[Cu(Et2NCH2CH2NH2)(2)center dot H2O](NO3)(2) complex: Experimental with DFT combinationcitations
- 2017Two closely related 2-(benzofuran-2-yl)-2-oxoethyl benzoates: structural differences and C—H...O hydrogen-bonded supramolecular assemblies
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article
Crystal interaction, XRD powder, and Hirshfeld surface analysis of S-benzyl-β-N-(1-(4-chlorophenyl) ethylidene) dithiocarbazate Schiff base
Abstract
The reaction of S-benzyldithiocarbazate with 4-chloroacetophenone afforded bidentate NS Schiff base (S.B) S-benzyl-β-N-(1-(4-chlorophenyl)ethylidene) dithiocarbazate, the thione tautomeric is very interesting, usually such Schiff base chelated to the metal center through neutral nitrogen at in the azomethine and the ionic sulfur of the thiol. The ligand structure has been confirmed by FT-IR, FAB-MS, UV-vis, PXRD and XRD-crystal. The main target of this work is to compare the XRD-interactions with the computed result of Hirshfeld surface analysis (HSA). Both HSA and XRD reflected the presence of the NH…S=C and CH….S=C. H-bonds as main interactions forces in crystal lattice of the desired ligand.