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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hélix-Nielsen, Claus
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Facile Fabrication of Flexible Ceramic Nanofibrous Membranes for Enzyme Immobilization and Transformation of Emerging Pollutantscitations
- 2023Facile Fabrication of Flexible Ceramic Nanofibrous Membranes for Enzyme Immobilization and Transformation of Emerging Pollutantscitations
- 2023Synthesis of magnetic nanoparticles with covalently bonded polyacrylic acid for use as forward osmosis draw agentscitations
- 2022Concentrating hexavalent chromium electroplating wastewater for recovery and reuse by forward osmosis using underground brine as draw solutioncitations
- 2021Employing the synergistic effect between aquaporin nanostructures and graphene oxide for enhanced separation performance of thin-film nanocomposite forward osmosis membranescitations
- 2021Impedance characterization of biocompatible hydrogel suitable for biomimetic lipid membrane applicationscitations
- 2021Impact of sodium hypochlorite on rejection of non-steroidal anti-inflammatory drugs by biomimetic forward osmosis membranescitations
- 2019Synthesis of Poly-Sodium-Acrylate (PSA)-Coated Magnetic Nanoparticles for Use in Forward Osmosis Draw Solutionscitations
- 2016Influence of feed composition and membrane fouling on forward osmosis performance
- 2015A reusable device for electrochemical applications of hydrogel supported black lipid membranescitations
- 2015A feasibility study of ultrafiltration/reverse osmosis (UF/RO)-based wastewater treatment and reuse in the metal finishing industrycitations
- 2012Tailoring Properties of Biocompatible PEG-DMA Hydrogels with UV Lightcitations
- 2011Surface Modifications of Support Partitions for Stabilizing Biomimetic Membrane Arrayscitations
- 2011Electrochemical characterization of hydrogels for biomimetic applicationscitations
Places of action
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article
Surface Modifications of Support Partitions for Stabilizing Biomimetic Membrane Arrays
Abstract
Black lipid membrane (BLM) formation across apertures in an ethylene tetra-fluoroethylene (ETFE) partition separating two aqueous compartments is an established technique for the creation of biomimetic membranes. Recently multi-aperture BLM arrays have attracted interest and in order to increase BLM array stability we studied the effect of covalently modifying the partition substrate using surface plasma polymerization with hydrophobic n-hexene, 1-decene and hexamethyldisiloxane (HMDSO) as modification groups. Average lifetimes across singlesided HMDSO modified partitions or using 1-decene modified partitions were similar and significantly lower than for arrays formed using untreated ETFE partitions. For single side n-hexene modification average membrane array lifetimes were not significantly changed compared to untreated ETFE. Double-sided n-hexene modification greatly improved average membrane array lifetimes compared to membrane arrays formed across untreated ETFE partitions. n-hexene modifications resulted in BLM membrane arrays which over time developed significantly lower conductance (Gm) and higher capacitance (Cm) values compared to the other membranes with the strongest effect for double sided modification. n-hexene modification is evident as a change in surface energy whereas the surface roughness does not change significantly. The concomitant low Gm and high Cm values for BLM arrays formed using double-sided n-hexene modification enable transmembrane ionic current recordings with a high signal-to-noise (s/n) ratio. We demonstratesd this by reconstituting gA and α-hemolysin (α-HL) into BLM arrays. The improvement in membrane array lifetime and s/n ratio demonstrates that surface plasma polymerization of the supporting partition can be used to increase the stability of biomimetic membrane arrays.