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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Stamboulis, Artemis
Imperial College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2023A Novel Approach for Powder Bed Fusion of Ceramics Using Two Laser Systemscitations
- 2022Processing and interpretation of core‐electron XPS spectra of complex plasma‐treated polyethylene‐based surfaces using a theoretical peak model
- 2021Antimicrobial bioceramics for biomedical applicationscitations
- 2021An Overview of Sputtering Hydroxyapatite for BiomedicalApplicationcitations
- 2019Mechanical testing of antimicrobial biocomposite coating on metallic medical implants as drug delivery systemcitations
- 2017Types of ceramics: Material classcitations
- 2017Types of ceramics : material class
- 2015Nano-hydroxyapatite deposition on titanium using peptide aptamers
- 2015Functionalization of biomedical surfaces by peptide aptamers
- 2014Electrospun Fibres of Polyhydroxybutyrate Synthesized by Ralstonia eutropha from Different Carbon Sourcescitations
- 2014Electrospun Fibres of Polyhydroxybutyrate Synthesized by Ralstonia eutropha from Different Carbon Sourcescitations
- 2014Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization
- 2014Nanoclay addition to a conventional glass ionomer cementscitations
- 2014Electrospun fibres of polyhydroxybutyrate synthesized by ralstonia eutropha from different carbon sourcescitations
- 2014Effect of nanoclay dispersion on the properties of a commercial glass ionomer cementcitations
- 2013Sol-Gel Preparation of Silica-Based Nano-Fibers for Biomédical Applications
- 2013Active screen plasma nitriding enhances cell attachment to polymer surfacescitations
- 2013Nitrogen plasma surface modification enhances cellular compatibility of aluminosilicate glasscitations
- 2012Durability and reliability of medical polymerscitations
- 2011An X-ray micro-fluorescence study to investigate the distribution of Al, Si, P and Ca ions in the surrounding soft tissue after implantation of a calcium phosphate-mullite ceramic composite in a rabbit animal modelcitations
- 2010Effect of active screen plasma nitriding on the biocompatibility of UHMWPE surfaces
- 2008Solid state MAS-NMR and FTIR study of barium containing alumino-silicate glasses
- 2007Real-time nucleation and crystallisation studies of a fluorapatite glass-ceramics using small-angle neutron scattering and neutron diffractioncitations
- 2007Structural characterization of ionomer glasses by multinuclear solid state MAS-NMR spectroscopycitations
- 2006The influence of montmorillonite clay reinforcement on the performance of a glass ionomer restorativecitations
- 2006Real Time Neutron Diffraction Studies of apatite glass ceramicscitations
- 2002Mechanical properties of biodegradable polymer sutures coated with bioactive glasscitations
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article
Real Time Neutron Diffraction Studies of apatite glass ceramics
Abstract
Apatite-mullite glass-ceramics have been developed based on SiO2-Al2O3-P2O5-CaOCaF2 glasses. The glasses crystallise to form fluorapatite (FAP) and mullite with an appropriate heat treatment. The crystallisation mechanism has been thought to occur via a prior amorphous phase separation. The aim of this study was to carry out real time neutron diffraction of apatite-mullite glass-ceramics in order to develop an understanding of the crystal growth and crystal dissolution phenomena in the temperature regime between 550 and 1200oC. The results show that during the initial stages of fluorapatite crystallisation pronounced line broadening was observed indicating crystallisation on a nanoscale. Mullite starts to crystallise once there is insufficient charge balancing cations in the glass to maintain aluminium in a four fold coordination state. As a result of this work it is suggested that the mechanism of crystal growth of FAP is thought to involve the dissolution of smaller FAP crystals during the crystal growth temperature followed by re-crystallisation of FAP on the remaining larger crystallites during cooling.