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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Bih, L. |
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Casati, R. |
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Kočí, Jan | Prague |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Shang, Hsien
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article
Microstructural and Chemical Investigations of Presolar Silicates from Diverse Stellar Environments
Abstract
We report the structural and chemical investigation of nine presolar silicate grains from the CH3/CB<SUB>b</SUB>3 chondrite Isheyevo and CR2 chondrite Northwest Africa (NWA) 801. Five of these grains belong to group 1, likely condensed in low- to intermediate-mass asymptotic giant branch (AGB) stars, super-AGB stars, or core-collapse supernovae, while the remaining four grains belong to group 4 and have a supernova origin. The advanced transmission electron microscopy and associated electron spectroscopy analyses show a diverse range of chemical and structural compositions for presolar silicates. Two GEMS (glass with embedded metal and sulfide)-like silicates, each from different groups, condensed under nonequilibrium conditions in stellar outflows. Two nonstoichiometric silicates from group 1 have dissimilar formation and alteration histories. An amorphous silicate from group 1 with olivine-like [(Mg,Fe)<SUB>2</SUB>SiO<SUB>4</SUB>] composition likely formed as a crystalline olivine that subsequently amorphized in the interstellar medium. An oldhamite (CaS) grain within a stoichiometric enstatite (MgSiO<SUB>3</SUB>) from group 1 probably formed by heterogeneous condensation in circumstellar outflows. Of the two crystalline grains from group 4, one is an antigorite [(Mg,Fe)<SUB>3</SUB>Si<SUB>2</SUB>O<SUB>5</SUB>(OH)<SUB>4</SUB>], while the other is a nontronite [Na,Fe<SUB>2</SUB>(Si,Al)<SUB>4</SUB>O<SUB>10</SUB>(OH)<SUB>2</SUB>.nH<SUB>2</SUB>O], both formed as a crystalline forsterite and later altered to have hydrated silicate composition. A group-4 silicate has a chemical composition similar to a low Ca-pyroxene [(Ca,Mg)(Si,Al)<SUB>2</SUB>O<SUB>6</SUB>]. Our data imply that presolar grains from different groups can have a similar range of grain-formation conditions....