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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bernstorff, Sigrid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2023Modulation of electronic and ionic conduction in mixed polymer conductors via additive engineering: Towards targeted applications under varying humiditycitations
- 2023Morphological Insights into the Degradation of Perovskite Solar Cells under Light and Humiditycitations
- 2023Ionic Liquid-Induced Inversion of the Humidity-Dependent Conductivity of Thin PEDOT:PSS Filmscitations
- 2022In Situ Observation of Morphological and Oxidation Level Degradation Processes within Ionic Liquid Post-treated PEDOT:PSS Thin Films upon Operation at High Temperaturescitations
- 2021Correlation of Thermoelectric Performance, Domain Morphology and Doping Level in PEDOT:PSS Thin Films Post‐Treated with Ionic Liquidscitations
- 2021Hollow metal island films as plasmonic sensors produced by galvanic replacementcitations
- 2020In Operando GISAXS and GIWAXS Stability Study of Organic Solar Cells Based on PffBT4T‐2OD:PC71BM with and without Solvent Additivecitations
- 2020Tailoring Morphology Compatibility and Device Stability by Adding PBDTTPD-COOH as Third Component to Fullerene-Based Polymer Solar Cellscitations
- 2019Self-Assembly in ultrahigh molecular weight sphere-forming diblock copolymer thin films under strong confinementcitations
- 2019Ionic Liquids as Post-Treatment Agents for Simultaneous Improvement of Seebeck Coefficient and Electrical Conductivity in PEDOT:PSS Filmscitations
- 2019Structure-function correlations in sputter deposited gold/fluorocarbon multilayers for tuning optical responsecitations
- 2019Application of GISAXS in the Investigation of Three-Dimensional Lattices of Nanostructurescitations
- 2019In-Operando Study of the Effects of Solvent Additives on the Stability of Organic Solar Cells Based on PTB7-Th:PC71BMcitations
- 2018Wet Imprinting of Channel‐Type Superstructures in Nanostructured Titania Thin Films at Low Temperatures for Hybrid Solar Cellscitations
- 2017Ta<sub>2</sub>N<sub>3</sub> nanocrystals grown in Al<sub>2</sub>O<sub>3</sub> thin layerscitations
- 2017Dislocation Movement Induced by Molecular Relaxations in Isotactic Polypropylenecitations
- 2017Codependence between Crystalline and Photovoltage Evolutions in P3HT:PCBM Solar Cells Probed with in-Operando GIWAXScitations
- 2017Pore size control of block copolymer-templated sol–gel-synthesized titania films deposited via spray coatingcitations
- 2016Influence of RF excitation during pulsed laser deposition in oxygen atmosphere on the structural properties and luminescence of nanocrystalline ZnO:Al thin filmscitations
- 2016Influence of RF excitation during pulsed laser deposition in oxygen atmosphere on the structural properties and luminescence of nanocrystalline ZnO:Al thin filmscitations
- 2016A Low Temperature Route toward Hierarchically Structured Titania Films for Thin Hybrid Solar Cellscitations
- 2015Effect of Blend Composition and Additives on the Morphology of PCPDTBT:PC 71 BM Thin Films for Organic Photovoltaicscitations
- 2015In operando morphology investigation of inverted bulk heterojunction organic solar cells by GISAXScitations
- 2015A Closer Look into Two-Step Perovskite Conversion with X-ray Scatteringcitations
Places of action
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article
Ta<sub>2</sub>N<sub>3</sub> nanocrystals grown in Al<sub>2</sub>O<sub>3</sub> thin layers
Abstract
<jats:p>Tantalum nitride nanoparticles (NPs) and cubic bixbyite-type Ta<jats:sub>2</jats:sub>N<jats:sub>3</jats:sub> nanocrystals (NCs) were grown in (Ta–N+Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>)/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> periodic multilayers (MLs) after thermal treatment. The MLs were prepared by magnetron deposition at room temperature and characterized using grazing incidence small-angle X-ray scattering (GISAXS), X-ray reflectivity (XRR), grazing incidence X-ray diffraction (GIXRD), secondary ion mass spectrometry (SIMS) and X-ray photoelectron spectroscopy (XPS). We found amorphous tantalum nitride NPs at 600–800 °C, with a high degree of ordering along the surface normal and short-range ordering within the layers containing tantalum (metallic layers). At an even higher annealing temperature of 900 °C the NPs crystallize in the rare and relatively unexplored Ta<jats:sub>2</jats:sub>N<jats:sub>3</jats:sub> phase. However, the environment, morphology and spatial ordering of the NCs depend on the thickness of the metallic layers. For 12 nm thick metallic layers, the Ta<jats:sub>2</jats:sub>N<jats:sub>3</jats:sub> NCs have an average diameter of 6 nm and they are confined and short-range ordered within the metallic layers. When the metallic layers are thinner, the NCs grow over 20 nm in diameter, show no spatial ordering, while the periodic structure of the ML was completely destroyed. The results presented here demonstrate a self-assembly process of tantalum nitride NPs, the morphological properties of which depend on the preparation conditions. This can be used as a generic procedure to realize highly tunable and designable optical properties of thin films containing transition-metal nitride nanocrystals.</jats:p>