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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fichtner, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020Metal (boro-) hydrides for high energy density storage and relevant emerging technologiescitations
- 2019Oxygen Activity in Li-Rich Disordered Rock-Salt Oxide and the Influence of LiNbO$_{3}$ Surface Modification on the Electrochemical Performancecitations
- 2018Effect of oxidizer in the synthesis of NiO anchored nanostructure nickel molybdate for sodium-ion batterycitations
- 2015Development of new anode composite materials for fluoride ion batteries
- 2015Single step tranformation of sulphur to Li₂S₂/Li₂S in Li-S batteries
- 2013A facile synthesis of a carbon-encapsulated Fe₃O₄ nanocomposite and its performance as anode in lithium-ion batteriescitations
- 2013Influence of particle size and fluorination ratio of CFₓ precursor compounds on the electrochemical performance of C-FeF₂ nanocomposites for reversible lithium storagecitations
- 2012Synthesis and characterisation of a mesoporous carbon/calcium borohydride nanocomposite for hydrogen storagecitations
- 2012Tailored heat transfer characteristics of pelletized LiNH2-MgH2 and NaAlH4 hydrogen storage materialscitations
- 2011On the decomposition of the 0.6LiBH4-0.4Mg(BH4)2 eutectic mixture for hydrogen storagecitations
- 2011Modified synthesis of [Fe/LiF/C] nanocomposites, and its application as conversion cathode material in lithium batteriescitations
- 2009Thermal coupling of a high temperature PEM fuel cell with a complex hydride tankcitations
- 2004Nanotechnological approaches in the development of materials for hydrogen storage
- 2004Nanotechnological aspects in materials for hydrogen storage
Places of action
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article
Influence of particle size and fluorination ratio of CFₓ precursor compounds on the electrochemical performance of C-FeF₂ nanocomposites for reversible lithium storage
Abstract
Systematical studies of the electrochemical performance of CFx-derived carbon–FeF2 nanocomposites for reversible lithium storage are presented. The conversion cathode materials were synthesized by a simple one-pot synthesis, which enables a reactive intercalation of nanoscale Fe particles in a CFx matrix, and the reaction of these components to an electrically conductive C–FeF2 compound. The pretreatment and the structure of the utilized CFx precursors play a crucial role in the synthesis and influence the electrochemical behavior of the conversion cathode material. The particle size of the CFx precursor particles was varied by ball milling as well as by choosing different C/F ratios. The investigations led to optimized C–FeF2 conversion cathode materials that showed specific capacities of 436 mAh/g at 40 °C after 25 cycles. The composites were characterized by Raman spectroscopy, X-Ray diffraction measurements, electron energy loss spectroscopy and TEM measurements. The electrochemical performances of the materials were tested by galvanostatic measurements.