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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Escudero-Escribano, María
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Toward understanding CO oxidation on high-entropy alloy electrocatalystscitations
- 2024Preparation and characterization of bimetallic and multimetallic nanostructured materials for electrocatalysis
- 2024Composition effects of electrodeposited Cu-Ag nanostructured electrocatalysts for CO2 reductioncitations
- 2024Composition effects of electrodeposited Cu-Ag nanostructured electrocatalysts for CO 2 reductioncitations
- 2024Preparation of Tunable Cu−Ag Nanostructures by Electrodeposition in a Deep Eutectic Solventcitations
- 2023Nanostructured Ir-based electrocatalysts for oxygen evolution prepared by galvanic displacement of Co and Nicitations
- 2022Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticlescitations
- 2022Pd-Au Nanostructured Electrocatalysts with Tunable Compositions for Formic Acid Oxidationcitations
- 2022Pd-Au Nanostructured Electrocatalysts with Tunable Compositions for Formic Acid Oxidationcitations
- 2021Preparation of high surface area Cu-Au bimetallic nanostructured materials by co-electrodeposition in a deep eutectic solventcitations
Places of action
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article
Surfactant-free syntheses and pair distribution function analysis of osmium nanoparticles
Abstract
A surfactant-free synthesis of precious metal nanoparticles (NPs) performed in alkaline low-boiling-point solvents has been recently reported. Monoalcohols are here investigated as solvents and reducing agents to obtain colloidal Os nanoparticles by using low-temperature (<100 °C) surfactant-free syntheses. The effect of the precursor (OsCl 3 or H 2 OsCl 6 ), precursor concentration (up to 100 mM), solvent (methanol or ethanol), presence or absence of a base (NaOH), and addition of water (0 to 100 vol %) on the resulting nanomaterials is discussed. It is found that no base is required to obtain Os nanoparticles as opposed to the case of Pt or Ir NPs. The robustness of the synthesis for a precursor concentration up to 100 mM allows for the performance of X-ray total scattering with pair distribution function (PDF) analysis, which shows that 1–2 nm hexagonal close packed (hcp) NPs are formed from chain-like [OsO x Cl y ] complexes.