| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mañas-Valero, Samuel
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Proximity effects on the charge density wave order and superconductivity in single-layer NbSe2citations
- 2024A local study of the transport mechanisms in MoS2 layers for magnetic tunnel junctionscitations
- 2023Magnetic Imaging and Domain Nucleation in CrSBr Down to the 2D Limitcitations
- 2022Ultrafast coherent THz lattice dynamics coupled to spins in the van der Waals antiferromagnet FePS3
- 2021Proximity Effects on the Charge Density Wave Order and Superconductivity in Single-Layer NbSe2citations
- 2021Attosecond state-resolved carrier motion in quantum materials probed by soft x-ray XANEScitations
- 2021Proximity Effects on the Charge Density Wave Order and Superconductivity in Single-Layer NbSe 2citations
- 2019Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic frameworkcitations
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article
Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework
Abstract
<jats:p>The design of metal–organic frameworks (MOFs) incorporating electroactive guest molecules in the pores has become a subject of great interest in order to obtain additional electrical functionalities within the framework while maintaining porosity. Understanding the charge-transfer (CT) process between the framework and the guest molecules is a crucial step towards the design of new electroactive MOFs. Herein, we present the encapsulation of fullerenes (C<jats:sub>60</jats:sub>) in a mesoporous tetrathiafulvalene (TTF)-based MOF. The CT process between the electron-acceptor C<jats:sub>60</jats:sub> guest and the electron-donor TTF ligand is studied in detail by means of different spectroscopic techniques and density functional theory (DFT) calculations. Importantly, gas sorption measurements demonstrate that sorption capacity is maintained after encapsulation of fullerenes, whereas the electrical conductivity is increased by two orders of magnitude due to the CT interactions between C<jats:sub>60</jats:sub> and the TTF-based framework.</jats:p>