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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sodani, Khaled A. Alawi Al
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Publications (6/6 displayed)
- 2024Comparative Analysis of Gradient-Boosting Ensembles for Estimation of Compressive Strength of Quaternary Blend Concrete
- 2023Thermal properties, microstructure analysis, and environmental benefits of basalt fiber reinforced concrete
- 2023Thermal properties, microstructure analysis, and environmental benefits of basalt fiber reinforced concretecitations
- 2022Microstructural Characteristics, Modeling of Mechanical Strength and Thermal Performance of Industrial Waste Glass Blended Concretecitations
- 2022Performances of the Synergy of Silica Fume and Waste Glass Powder in Ternary Blended Concretecitations
- 2022Acid Resistance of Alkali-Activated Natural Pozzolan and Limestone Powder Mortarcitations
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article
Acid Resistance of Alkali-Activated Natural Pozzolan and Limestone Powder Mortar
Abstract
<jats:p>The development of sustainable, environmentally friendly alkali-activated binder has emerged as an alternative to ordinary Portland cement. The engineering and durability properties of alkali-activated binder using various precursor combinations have been investigated; however, no study has focused on the impact of high-volume natural pozzolan (NP) on the acid resistance of alkali-activated NP and limestone powder. Therefore, the current study assesses the impact of high-volume natural pozzolan (volcanic ash) on the durability properties of alkali-activated natural pozzolan (NP) and limestone powder (LSP) mortar by immersion in 6% H2SO4 for 365 days. The samples were prepared with different binder ratios using alkaline activators (10 M NaOH(aq) and Na2SO4) combined in a 1:1 ratio and cured at 75 . NP was combined with the LSP at three different combinations: NP:LSP = 40:60 (AAN40L60), 50:50 (AAN50L50), and 60:40 (AAN60L40), representing low-volume, balanced, and high-volume binder combinations. Water absorption, weight change, and compressive strength were examined. The microstructural changes were also investigated using FTIR, XRD, and SEM/EDS characterization tools. Visual examination showed insignificant deterioration in the sample with excess natural pozzolan (AAN60L40) after 1 year of acid exposure, and the maximum residual strengths were 20.8 MPa and 6.68 MPa in AAN60L40 and AAN40L60 with mass gain (1.37%) and loss (10.64%), respectively. The high sulfuric acid resistance of AAN60L40 mortar was attributed to the high Ca/Si = 10 within the C-A-S-H and N-A-S-H formed. The low residual strength recorded in AAN40L60 was a result of gypsum formation from an acid attack of calcium-dominated limestone powder. The controlling factor for the resistance of the binder to acid corrosion was the NP/LSP ratio, whose factor below 0.6 caused significant debilitating effects.</jats:p>