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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lehmusto, Juho
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024A novel methodology for monitoring low-temperature corrosion caused by hygroscopic salts using linear polarization resistancecitations
- 2024Analytical and applied pyrolysis of challenging biomass feedstockscitations
- 2024Analytical and applied pyrolysis of challenging biomass feedstocks:Effect of pyrolysis conditions on product yield and compositioncitations
- 2023The effect of Cl, Br, and F on high-temperature corrosion of heat-transfer alloyscitations
- 2022Comprehensive insights into competitive oxidation/sulfidation reactions on binary ferritic alloys at high temperaturescitations
- 2022Amino Acids Reduce Mild Steel Corrosion in Used Cooking Oilscitations
- 2022Metal Rod Surfaces after Exposure to Used Cooking Oilscitations
- 2021Should the oxygen source be considered in the initiation of KCl-induced high-temperature corrosion?citations
- 2021Effect of annealing and supercritical CO 2 exposure at 750 °C on the tensile properties of stainless steel and Ni-based structural alloyscitations
- 2021Superheater deposits and corrosion in temperature gradient – Laboratory studies into effects of flue gas composition, initial deposit structure, and exposure timecitations
- 2017The effect of temperature on the formation of oxide scales regarding commercial superheater steelscitations
- 2015The Effect of Pretreatment on the Corrosion Resistance of Superheater Materialscitations
- 2015Comparison of High-Temperature Oxidation Onset Behavior of Sanicro 28 Steel with KCl, NaCl and K<sub>2</sub>CO<sub>3</sub>
- 2011Detailed Studies on the High Temperature Corrosion Reactions between Potassium Chloride and Metallic Chromiumcitations
Places of action
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article
Metal Rod Surfaces after Exposure to Used Cooking Oils
Abstract
Used cooking oils (UCOs) have a high potential as renewable fuels for the maritime shipping industry. However, their corrosiveness during storage and usage are some of the concerns yet to be investigated for addressing compatibility issues. Thus, the corrosion of steels and copper exposed to the UCOs was studied through the immersion of metal rods for different periods. The<br/>changes on the rod surfaces were analyzed with a scanning electron microscope (SEM). After the immersion, the copper concentration dissolved in the bio‐oils was measured using inductively coupled plasma‐optical emission spectrometry (ICP‐OES). The free fatty acids and glycerides were analyzed using gas chromatography with flame ionization detection (GC‐FID). The acid number (AN), water concentration, as well as density and kinematic viscosity of the bio‐oils were determined with standard methods. The UCOs with the highest water content were corrosive, while the oils with lower water concentrations but higher ANs induced lower corrosion. After mixing two different UCOs, the metal corrosion decreased with an increasing concentration of the oil with lower corrosive properties. The lower corrosion properties were most likely due to the monounsaturated fatty acids, e.g., oleic acid in oils. These acids formed a barrier layer on the rod surfaces, thereby inhibiting the permeation of oxygen and water to the surface. Even adding 0.025 wt% of tert‐butylamine decreased the corrosivity of UCO against polished steel rod. The results suggested that mixing several oil batches and adding a suitable inhibitor reduces the potential corrosive properties of UCOs.