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Publications (7/7 displayed)
- 2022Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solutioncitations
- 2021Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formatescitations
- 2019Hybrid lead halide [(CH3)2NH2]PbX3 (X = Cl- and Br-) hexagonal perovskites with multiple functional propertiescitations
- 2013Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formatecitations
- 2011Studies on the power factor of (Ba,Sr)Co2+xRu4−xO11 compoundscitations
- 2009Magnetoelectric behavior in the complex CaMn7O12 perovskitecitations
- 2008Charge ordering and dielectric properties in the near half-doped Pr0.79Na0.21MnO3 perovskitecitations
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article
Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates
Abstract
<jats:p>A systematic study of the thermal decomposition of hybrid perovskites of formula [AH][M(HCOO)3] under inert atmosphere was performed by means of thermogravimetry and simultaneous infrared spectroscopy of the evolved gases. The influence of: (i) the metal ion of the [M(HCOO)3]- framework and (ii) the guest [AH]+ cation, in the composition of the final residue was evaluated. In this work, it has been demonstrated that these materials can be used as precursors of metal or metal-oxide compounds—obtained free of carbon—, and that the composition of the final residue is determined by the standard reduction potential of the metal cation of the framework.</jats:p>