Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (3/3 displayed)

  • 2022Investigation on Sensing Performance of Highly Doped Sb/SnO219citations
  • 2021Synthesis, Material and Electrical Characterization Combined with DFT Calculations of Reduced SnO2-x1citations
  • 2020Influence of Oxygen Vacancies in Gas Sensors Based on Metal-Oxide Semiconductors: A First-Principles Study8citations

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Casotti, Davide
2 / 3 shared
Guidi, Vincenzo
3 / 24 shared
Vanzetti, Lia
1 / 7 shared
Fabbri, Barbara
3 / 10 shared
Feng, Zhifu
1 / 3 shared
Gaiardo, Andrea
3 / 14 shared
Caramori, Stefano
1 / 17 shared
Fioravanti, Simona
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Rota, Alberto
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Valt, Matteo
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Ciana, Michele Della
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Malagu, Cesare
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Pepponi, Giancarlo
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Bellutti, Pierluigi
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Co-Authors (by relevance)

  • Casotti, Davide
  • Guidi, Vincenzo
  • Vanzetti, Lia
  • Fabbri, Barbara
  • Feng, Zhifu
  • Gaiardo, Andrea
  • Caramori, Stefano
  • Fioravanti, Simona
  • Rota, Alberto
  • Valt, Matteo
  • Ciana, Michele Della
  • Malagu, Cesare
  • Pepponi, Giancarlo
  • Bellutti, Pierluigi
  • Cruciani, Giuseppe
OrganizationsLocationPeople

article

Investigation on Sensing Performance of Highly Doped Sb/SnO2

  • Casotti, Davide
  • Guidi, Vincenzo
  • Vanzetti, Lia
  • Fabbri, Barbara
  • Feng, Zhifu
  • Gaiardo, Andrea
  • Caramori, Stefano
  • Fioravanti, Simona
  • Rota, Alberto
  • Valt, Matteo
  • Krik, Soufiane
  • Ciana, Michele Della
Abstract

Tin dioxide (SnO2) is the most-used semiconductor for gas sensing applications. However, lack of selectivity and humidity influence limit its potential usage. Antimony (Sb) doped SnO2 showed unique electrical and chemical properties, since the introduction of Sb ions leads to the creation of a new shallow band level and of oxygen vacancies acting as donors in SnO2. Although low-doped SnO2:Sb demonstrated an improvement of the sensing performance compared to pure SnO2, there is a lack of investigation on this material. To fill this gap, we focused this work on the study of gas sensing properties of highly doped SnO2:Sb. Morphology, crystal structure and elemental composition were characterized, highlighting that Sb doping hinders SnO2 grain growth and decreases crystallinity slightly, while lattice parameters expand after the introduction of Sb ions into the SnO2 crystal. XRF and EDS confirmed the high purity of the SnO2:Sb powders, and XPS highlighted a higher Sb concentration compared to XRF and EDS results, due to a partial Sb segregation on superficial layers of Sb/SnO2. Then, the samples were exposed to different gases, highlighting a high selectivity to NO2 with a good sensitivity and a limited influence of humidity. Lastly, an interpretation of the sensing mechanism vs. NO2 was proposed.

Topics
  • impedance spectroscopy
  • morphology
  • grain
  • x-ray photoelectron spectroscopy
  • Oxygen
  • semiconductor
  • Energy-dispersive X-ray spectroscopy
  • tin
  • crystallinity
  • grain growth
  • X-ray fluorescence spectroscopy
  • Antimony