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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wojkiewicz, Jean-Luc
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Publications (5/5 displayed)
- 2022The Impact of Interfacial Interactions on Structural, Electronic, and Sensing Properties of Poly(3‐methylthiophene) in Core‐Shell Nanocomposites. Application for Chemical Warfare Agent Simulants Detectioncitations
- 2021Conductive Polymer Composites for Hydrogen Sulphide Sensors Working at Sub-PPM Level and Room Temperaturecitations
- 2021Polyaniline Nanocomposites for Hydrogen Sulfide Detection at ppb Level
- 2018From drifting polyaniline sensor to accurate sensor array for breath analysiscitations
- 2018Polyaniline nanocomposites based sensor array for breath ammonia analysis. Portable e-nose approach to non-invasive diagnosis of chronic kidney diseasecitations
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article
Conductive Polymer Composites for Hydrogen Sulphide Sensors Working at Sub-PPM Level and Room Temperature
Abstract
Hybrid composites based on tin chloride and the conductive polymers, polyaniline (PAni) and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), were integrated into high-performance hydrogen sulphide (H2S) gas sensors working at room temperature. The morphology and chemical properties were studied by scanning and transmission electron microscopy (SEM, TEM), energy dispersive spectroscopy (EDS) and Fourier-transform infrared (FTIR). The composites demonstrated a slightly porous nanostructure and strong interactions between the polymers and the metal salt, which slightly dopes PAni. The hybrid sensors exhibited a very low detection limit (<85 ppb), fast response, repeatability, reproducibility and stability over one month. Moreover, this work presents how calibration based on the derivative of the signal can give hybrid sensors the ability to quantify the concentration of targeted gas, even during continuous variation of the analyte concentration. Finally, the effect of interfering species, such as water and ammonia, is discussed.