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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Niedziałkowski, Paweł
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Publications (7/7 displayed)
- 2020Efficient method for the concentration determination of Fmoc groups incorporated in the core-shell materials by Fmoc-glycinecitations
- 2020Electrochemical performance of thin free-standing boron-doped diamond nanosheet electrodescitations
- 2020Dansyl-labelled Ag@SiO2 core-shell nanostructures-synthesis, characterization, and metal-enhanced fluorescencecitations
- 2019Understanding the origin of high corrosion inhibition efficiency of bee products towards aluminium alloys in alkaline environmentscitations
- 2018Optical monitoring of electrochemical processes with ITO-based lossy-mode resonance optical fiber sensor applied as an electrodecitations
- 2018Optical detection of ketoprofen by its electropolymerization on an indium tin oxide-coated optical fiber probecitations
- 2017Characteristics of multiwalled carbon nanotubes-rhenium nanocomposites with varied rhenium mass fractions citations
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article
Optical detection of ketoprofen by its electropolymerization on an indium tin oxide-coated optical fiber probe
Abstract
In this work an application of optical fiber sensors for real-time optical monitoring of electrochemical deposition of ketoprofen during its anodic oxidation is discussed. The sensors were fabricated by reactive magnetron sputtering of indium tin oxide (ITO) on a 2.5 cm-long core of polymer-clad silica fibers. ITO tuned in optical properties and thickness allows for achieving a lossy-mode resonance (LMR) phenomenon and it can be simultaneously applied as an electrode in an electrochemical setup. The ITO-LMR electrode allows for optical monitoring of changes occurring at the electrode during electrochemical processing. The studies have shown that the ITO-LMR sensor’s spectral response strongly depends on electrochemical modification of its surface by ketoprofen. The effect can be applied for real-time detection of ketoprofen. The obtained sensitivities reached over 1400 nm/M (nm·mg−1·L) and 16,400 a.u./M (a.u.·mg−1·L) for resonance wavelength and transmission shifts, respectively. The proposed method is a valuable alternative for the analysis of ketoprofen within the concentration range of 0.25–250 μg mL−1, and allows for its determination at therapeutic and toxic levels. The proposed novel sensing approach provides a promising strategy for both optical and electrochemical detection of electrochemical modifications of ITO or its surface by various compounds.