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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Müller, Peter
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Thermal stability of electron beam welded AlCoCrFeNi2.1 alloy
- 2021Extension of Process Limits with Bidirectional Deep Drawingcitations
- 2020Single crystal growth of water-soluble metal complexes with the help of the nano-crystallization methodcitations
- 2020Recovery of Molybdenum, Chromium, Tungsten, Copper, Silver, and Zinc from Industrial Waste Waters Using Zero-Valent Iron and Tailored Beneficiation Processescitations
- 2018Recovery of Metals from Industrial Waste Waters
- 2018Root cause analysis of deep drawing processes with superimposed low-frequency vibrations on servo-screw presses ; Ursachenanalyse bei Tiefziehprozessen mit niederfrequenter Schwingungsüberlagerung auf Servo-Spindelpressen
- 2018Data mining and machine learning methods applied to a numerical clinching model ; Data mining und maschinelle Lernverfahren für ein numerisches Clinchmodellcitations
- 2013Method for dynamic analysis of a servo-spindle press ; Methode zur dynamischen Analyse einer Servo-Spindelpresse
- 2008Columnar mesophases from half-discoid platinum cyclometalated metallomesogenscitations
- 2006Dark-field oxidative addition-based chemosensingcitations
- 2000Sol-gel derived nanocomposite materials for corrosion protection of aluminium alloys
Places of action
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article
Recovery of Molybdenum, Chromium, Tungsten, Copper, Silver, and Zinc from Industrial Waste Waters Using Zero-Valent Iron and Tailored Beneficiation Processes
Abstract
<p>Zero-valent iron (ZVI) has been used for water treatment for more than 160 years. However, passivation of its surface often constituted a problem which could only be tackled recently by the innovative Ferrodecont process using a fluidized bed reactor. In this study, pilot scale experiments for the removal of Mo, Cr, W, Cu, Ag and Zn from two industrial waste water samples and lab-scale experiments for the beneficiation of the abrasion products are presented to integrate the Ferrodecont process into a complete recycling process chain. Firstly, 38.5 % of Cu was removed from sample A, yielding abrasion products containing 33.1 wt% Cu as metallic copper (Cu) and various Cu compounds. The treatment of sample B removed 99.8 % of Mo, yielding abrasion products containing 17.8 wt% of Mo as amorphous phases or adsorbed species. Thermal treatment (1300 °C) of the abrasion product A indicated a reduction of delafossite to metallic Cu according to differential scanning calorimetry (DSC), thermogravimetry (TG) and X-ray diffraction (XRD), which was successfully separated from the magnetic iron phases. Hydrometallurgical treatment (1.5 M NaOH, 3 d, liquid:solid ratio (L:S) = 15:1) of sample B yielded aqueous extracts with Mo concentrations of 5820 to 6300 mgL-1. In conclusion, this corresponds to an up to 53-fold enrichment of Mo during the entire process chain.</p>