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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jastrząb, Renata
in Cooperation with on an Cooperation-Score of 37%
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Publications (7/7 displayed)
- 2019Preparation and characterization of long-term stable SERS active materials as potential supports for medical diagnosticcitations
- 2018Coordination properties of N,N′-bis(5-methylsalicylidene)-2-hydroxy-1,3-propanediamine with d- and f-electron ions: crystal structure, stability in solution, spectroscopic and spectroelectrochemical studiescitations
- 2018Carboxyl groups of citric acid in the process of complex formation with bivalent and trivalent metal ions in biological systemscitations
- 2017PVDF membrane morphology - Influence of polymer molecularweight and preparation temperaturecitations
- 2017Applications of silver nanoparticles stabilized and/or immobilized by polymer matrixescitations
- 2015Supramolecular polymer of Schiff base gadolinium complex: Synthesis, crystal structure and spectroscopic propertiescitations
- 2013Potentiometric Study of Lanthanide Salicylaldimine Schiff Base Complexescitations
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article
PVDF membrane morphology - Influence of polymer molecularweight and preparation temperature
Abstract
In this study, we successfully prepared nine non-woven, supported polyvinylidene fluoride (PVDF) membranes, using a phase inversion precipitation method, starting from a 15 wt % PVDF solution in N-methyl-2-pyrrolidone. Various membrane morphologies were obtained by using (1) PVDF polymers, with diverse molecular weights ranging from 300 to 700 kDa, and (2) different temperature coagulation baths (20, 40, and 60 ± 2 °C) used for the film precipitation. An environmental scanning electron microscope (ESEM) was used for surface and cross-section morphology characterization. An atomic force microscope (AFM) was employed to investigate surface roughness, while a contact angle (CA) instrument was used for membrane hydrophobicity studies. Fourier transform infrared spectroscopy (FTIR) results show that the fabricated membranes are formed by a mixture of TGTG' chains, in α phase crystalline domains, and all-TTTT trans planar zigzag chains characteristic to β phase. Moreover, generated results indicate that the phases' content and membrane morphologies depend on the polymer molecular weight and conditions used for the membranes' preparation. The diversity of fabricated membranes could be applied by the End User Industries for different applications.</p>