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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liska, Robert
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Color-Stable Formulations for 3D-Photoprintable Dental Materialscitations
- 2023Biodegradable, Self‐Reinforcing Vascular Grafts for In Situ Tissue Engineering Approachescitations
- 2023Group transfer polymerization in bulk methacrylatescitations
- 2022Maleimide-styrene-butadiene terpolymerscitations
- 2021Heterotelechelic poly(propylene oxide) as migration-inhibited toughening agent in hot lithography based additive manufacturingcitations
- 2018Wavelength-optimized Two-Photon Polymerization Using Initiators Based on Multipolar Aminostyryl-1,3,5-triazinescitations
- 2017Polymers for 3D printing and customized additive manufacturingcitations
- 2017Polymers for 3D printing and customized additive manufacturingcitations
- 2017Evaluation of Difunctional Vinylcyclopropanes as Reactive Diluents for the Development of Low‐Shrinkage Compositescitations
- 2016Tough Photopolymers Based on Vinyl Esters for Biomedical Applicationscitations
- 2013Three-Dimensional Microfabrication of Protein Hydrogels via Two-Photon-Excited Thiol-Vinyl Ester Photopolymerizationcitations
- 2011Lithographiebasierte Fertigung keramischer Bauteile
- 2008Photopolymers with tunable mechanical properties processed by laser-based high-resolution stereolithography
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article
Color-Stable Formulations for 3D-Photoprintable Dental Materials
Abstract
<jats:p>Color stability is crucial for dental materials to ensure they perfectly match a patient’s tooth color. This is particularly challenging in photoresist-based additive manufacturing. Although some studies have addressed this issue, the exact causes of discoloration and ways to minimize it remain unclear. In this study, the intrinsic causes of discoloration in materials intended for 3D printing are investigated by examining thin-film samples (1200 µm) of various compositions, which are stored under different conditions. The samples are evaluated by measuring the UV-Vis absorption spectra at regular intervals to monitor changes. The findings reveal that both the composition of the formulations and the storage conditions significantly influence the discoloration behavior. Furthermore, methods have been developed to reduce or completely prevent discoloration. The use of photoinitiators with sterically demanding benzoyl moieties, as well as the addition of stabilizers, effectively decreases the intensity of emerging discoloration. Furthermore, incorporating the oxidizing agent cumene hydroperoxide (CHP) results in materials that maintain color stability.</jats:p>