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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Harabagiu, Valeria
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Publications (7/7 displayed)
- 2023Magnetic Ionotropic Hydrogels Based on Carboxymethyl Cellulose for Aqueous Pollution Mitigationcitations
- 2023Synthesis and Properties of Modified Biodegradable Polymers Based on Caprolactonecitations
- 2015Nanosized Spinel Ferrites Synthesized by Sol-Gel Autocombustion for Optimized Removal of Azo Dye from Aqueous Solutioncitations
- 2013Surface Modification of the Polyimide Films by Electrical Discharges in Watercitations
- 2013Comparison study of TEMPO and phthalimide-N-oxyl (PINO) radicals on oxidation efficiency toward cellulosecitations
- 2013Chemical modification and characterization of poly(ethylene terephthalate) surfaces for collagen immobilizationcitations
- 2009Inclusion complexes of γ-cyclodextrin and carboxyl-modified γ-cyclodextrin with C60: Synthesis, characterization and controlled release application via microgelscitations
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article
Synthesis and Properties of Modified Biodegradable Polymers Based on Caprolactone
Abstract
<jats:p>In this paper, the synthesis and characterization of two polycaprolactone-polydimethylsiloxane (PDMS-CL) copolymers with biodegradable properties are reported. A comparative study was carried out using an aminopropyl-terminated polydimethylsiloxane macro-initiator (APDMS) with two different molecular weights. The copolymers (PDMS-CL-1 and PDMS-CL-2) were obtained by ring-opening polymerization of ɛ-caprolactone using APDMS as initiators and stannous 2-ethylhexanoate as a catalyst. The copolymer’s structures were confirmed by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (1H-NMR) spectra, and energy dispersion spectroscopy (EDX). Surface morphology was investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The hydrophobic properties of the copolymers were demonstrated by the water contact angle and water vapor sorption capacity. Additionally, biological tests were conducted on San Marzano type tomato plants (Lypercosium esculentum) to assess the synthesized copolymers’ susceptibility to the environment in terms of biological stability and metabolic activity. The biodegradation of PDMS-CL-1 and PDMS-CL-2 copolymers does not have a dangerous effect on the metabolic activity of plants, which makes it a convenient product in interaction with the environment.</jats:p>