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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ruiz-Rubio, Leire
University of the Basque Country
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Enhanced Electrochemiluminescence at the Gas/Liquid Interface of Bubbles Propelled into Solutioncitations
- 2024Advancing Food Packaging: Exploring Cyto-Toxicity of Shape Memory Polyurethanescitations
- 2024Biodegradable Natural Hydrogels for Tissue Engineering, Controlled Release, and Soil Remediationcitations
- 2023Sustainable Bio-Based Epoxy Resins with Tunable Thermal and Mechanic Properties and Superior Anti-Corrosion Performancecitations
- 2023Graphene-Enhanced Methacrylated Alginate Gel Films for Sustainable Dye Removal in Water Purificationcitations
- 2021Photocurable temperature activated humidity hybrid sensing materials for multifunctional coatingscitations
- 2021Laser-activated screen-printed carbon electrodes for enhanced dopamine determination in the presence of ascorbic and uric acidcitations
- 2021Design of epoxy-silica hybrids based on cycloaliphatic diol of natural origin for conservation of lithic materialscitations
- 2021Laser-induced highly oriented pyrolytic graphite for high-performance screen-printed electrodescitations
- 2020Polysaccharide-Based In Situ Self-Healing Hydrogels for Tissue Engineering Applicationscitations
- 2019The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Techniquecitations
Places of action
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article
Sustainable Bio-Based Epoxy Resins with Tunable Thermal and Mechanic Properties and Superior Anti-Corrosion Performance
Abstract
<jats:p>Bio-based epoxy thermoset resins have been developed from epoxidized soybean oil (ESO) cured with tannic acid (TA). These two substances of vegetable origin have been gathering attention due to their accessibility, favorable economic conditions, and convenient chemical functionalization. TA’s suitable high phenolic functionalization has been used to crosslink ESO by adjusting the −OH (from TA):epoxy (from ESO) molar ratio from 0.5:1 to 2.5:1. By means of Fourier-transform infrared spectroscopy, resulting in thermosets that evidenced optimal curing properties under moderate conditions (150–160 °C). The thermogravimetric analysis of the cured resins showed thermal stability up to 261 °C, with modulable mechanical and thermal properties determined by differential scanning calorimetry, dynamical mechanical thermal analysis, and tensile testing. Water contact angle measurements (83–87°) and water absorption tests (0.6–4.5 initial weight% intake) were performed to assess the suitability of the resins as waterproof coatings. Electrochemical impedance spectroscopy measurements were performed to characterize the anti-corrosive capability of these coatings on carbon steel substrates. Excellent barrier properties have been demonstrated due to the high electrical isolation and water impermeability of these oil-based coatings, without signs of deterioration over 6 months of immersion in a 3.5 wt.% NaCl solution. These results demonstrate the suitability of the developed materials as anti-corrosion coatings for specific applications.</jats:p>