Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Graz University of Technology

in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (5/5 displayed)

  • 2024Transition metal azahemiporphycenes as singlet oxygen sensitizers1citations
  • 2023Exploring Aromatic S-Thioformates as Photoinitiators2citations
  • 2023On‐Demand Activation of Transesterification by Chemical Amplification in Dynamic Thiol‐Ene Photopolymers7citations
  • 2022Bis(acyl)phosphine Oxides as Stoichiometric Photo‐Reductants for Copper Nanoparticle Synthesis: Efficiency and Kinetics1citations
  • 2019Electrochemical Fixation of Nitrogen and Its Coupling with Biomass Valorization with a Strongly Adsorbing and Defect Optimized Boron-Carbon-Nitrogen Catalyst63citations

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Chart of shared publication
Gagnon, Kevin J.
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Rousselin, Yoann
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Alemayehu, Abraham B.
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Borisov, Sergey
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Ghosh, Abhik
1 / 2 shared
Cruz, Gema Guedes De La
2 / 2 shared
Haas, Michael
1 / 5 shared
Pueschmann, Sabrina
1 / 1 shared
Griesser, Thomas
2 / 9 shared
Rieger, Paul
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Reisinger, David
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Alabiso, Walter
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Schlögl, Sandra
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Grützmacher, Hansjörg
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Gescheidt, Georg
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Oschatz, Martin
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Heil, T.
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Antonietti, Markus
1 / 9 shared
Qin, Qing
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Schmidt, J.
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Co-Authors (by relevance)

  • Gagnon, Kevin J.
  • Rousselin, Yoann
  • Alemayehu, Abraham B.
  • Borisov, Sergey
  • Ghosh, Abhik
  • Cruz, Gema Guedes De La
  • Haas, Michael
  • Pueschmann, Sabrina
  • Griesser, Thomas
  • Rieger, Paul
  • Reisinger, David
  • Alabiso, Walter
  • Sölle, Bernhard
  • Rossegger, Elisabeth
  • Schlögl, Sandra
  • Grützmacher, Hansjörg
  • Gescheidt, Georg
  • Oschatz, Martin
  • Heil, T.
  • Antonietti, Markus
  • Qin, Qing
  • Schmidt, J.
OrganizationsLocationPeople

article

Exploring Aromatic S-Thioformates as Photoinitiators

  • Cruz, Gema Guedes De La
  • Haas, Michael
  • Pueschmann, Sabrina
  • Griesser, Thomas
  • Rieger, Paul
  • Schmallegger, Max
Abstract

<p>Thiyl radicals were generated from aromatic S-thioformates by photolysis. The corresponding photo-initiated decarbonylation allows initiating polymerization reactions in both acrylate- and thiol-acrylate-based resin systems. Compared to aromatic thiols, the introduction of the photolabile formyl group prevents undesired reactions with acrylate monomers allowing photoinitiators (PIs) with constant reactivity over storage. To demonstrate the potential of S-thioformates as PIs, the bifunctional molecule S,S′-(thiobis(4,1-phenylene))dimethanethioate (2b) was synthesized, providing reactivity under visible light excitation. Consequently, acrylate-based formulations could successfully be processed by digital light processing (DLP)-based stereolithography at 405 nm in high resolution.</p>

Topics
  • resin