| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Avgeropoulos, Apostolos
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Microwave-Assisted Extraction of Cellulose from Aloe Vera Plant Residue and Preparation of Cellulose Nanocrystal–Poly(vinyl alcohol) Hydrogelscitations
- 2023Thermal and Bulk Properties of Triblock Terpolymers and Modified Derivatives towards Novel Polymer Brushescitations
- 2023Synthesis and Structural Insight into Poly(dimethylsiloxane)-b-Poly(2-vinylpyridine) Copolymers
- 2022Microwave Synthesis, Characterization and Perspectives of Wood Pencil-Derived Carboncitations
- 2021Functionalization of single-walled carbon nanotubes with end-capped polystyrene via a single-step diels–alder cycloadditioncitations
- 2021Structure/Properties Relationship of Anionically Synthesized Diblock Copolymers “Grafted to” Chemically Modified Graphenecitations
- 2021Synthesis, Characterization and Structure Properties of Biobased Hybrid Copolymers Consisting of Polydiene and Polypeptide Segmentscitations
- 2021Synthesis, Characterization and Structure Properties of Biobased Hybrid Copolymers Consisting of Polydiene and Polypeptide Segmentscitations
- 2020Dendrons and Dendritic Terpolymers: Synthesis, Characterization and Self-Assembly Comparisoncitations
- 2019Examination of well ordered nanonetwork materials by real- and reciprocal-space imagingcitations
- 2018Metal (Ag/Ti)-Containing Hydrogenated Amorphous Carbon Nanocomposite Films with Enhanced Nanoscratch Resistance: Hybrid PECVD/PVD System and Microstructural Characteristicscitations
- 2017Indacenodithienothiophene-Based Ternary Organic Solar Cellscitations
- 2017Self-assembly of Polystyrene- b -poly(2-vinylpyridine)- b -poly(ethylene oxide) Triblock Terpolymerscitations
- 2016Nanocomposites based on nanostructured PI-b-PMMA copolymer and selectively placed PMMA-modified magnetic nanoparticles: Morphological and magnetic characterizationcitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone)citations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone):Enhanced interfacial bonding and optimized mechanical propertiescitations
- 2012Nanohybrids based on polymeric ionic liquid prepared from functionalized MWCNTs by modification of anionically synthesized poly(4-vinylpyridine)citations
Places of action
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article
Thermal and Bulk Properties of Triblock Terpolymers and Modified Derivatives towards Novel Polymer Brushes
Abstract
<jats:p>We report the synthesis of three (3) linear triblock terpolymers, two (2) of the ABC type and one (1) of the BAC type, where A, B and C correspond to three chemically incompatible blocks such as polystyrene (PS), poly(butadiene) of exclusively (~100% vinyl-type) -1,2 microstructure (PB1,2) and poly(dimethylsiloxane) (PDMS) respectively. Living anionic polymerization enabled the synthesis of narrowly dispersed terpolymers with low average molecular weights and different composition ratios, as verified by multiple molecular characterization techniques. To evaluate their self-assembly behavior, transmission electron microscopy and small-angle X-ray scattering experiments were conducted, indicating the effect of asymmetric compositions and interactions as well as inversed segment sequence on the adopted morphologies. Furthermore, post-polymerization chemical modification reactions such as hydroboration and oxidation were carried out on the extremely low molecular weight PB1,2 in all three terpolymer samples. To justify the successful incorporation of –OH groups in the polydiene segments and the preparation of polymeric brushes, various molecular, thermal, and surface analysis measurements were carried out. The synthesis and chemical modification reactions on such triblock terpolymers are performed for the first time to the best of our knowledge and constitute a promising route to design polymers for nanotechnology applications.</jats:p>