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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tarrés, Quim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Comparative Study on the Stiffness of Poly(lactic acid) Reinforced with Untreated and Bleached Hemp Fiberscitations
- 2023Lignin-Containing Cellulose Nanofibrils from TEMPO-Mediated Oxidation of Date Palm Waste: Preparation, Characterization, and Reinforcing Potentialcitations
- 2023Methodologies to Evaluate the Micromechanics Flexural Strength Properties of Natural-Fiber-Reinforced Composites: The Case of Abaca-Fiber-Reinforced Bio Polyethylene Compositescitations
- 2022Valorization ofkraft lignin from black liquor in the production of composite materials with poly(caprolactone) and natural stone groundwood fiberscitations
- 2022Processing Polymer Blends of Mater-Bi® and Poly-L-(Lactic Acid) for Blown Film Application with Enhanced Mechanical Strengthcitations
- 2020Effect of the Fiber Treatment on the Stiffness of Date Palm Fiber Reinforced PP Composites: Macro and Micromechanical Evaluation of the Young’s Moduluscitations
- 2020Lignin/poly(butylene succinate) composites with antioxidant and antibacterial properties for potential biomedical applicationscitations
- 2020Evolution of Interfacial Shear Strength and Mean Intrinsic Single Strength in Biobased Composites from Bio-Polyethylene and Thermo-Mechanical Pulp-Corn Stover Fiberscitations
- 2020Improved Process to Obtain Nanofibrillated Cellulose (CNF) Reinforced Starch Films with Upgraded Mechanical Properties and Barrier Charactercitations
- 2019Determination of Mean Intrinsic Flexural Strength and Coupling Factor of Natural Fiber Reinforcement in Polylactic Acid Biocompositescitations
- 2019Flexural Properties and Mean Intrinsic Flexural Strength of Old Newspaper Reinforced Polypropylene Compositescitations
- 2017Sugarcane bagasse reinforced compositescitations
Places of action
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article
Processing Polymer Blends of Mater-Bi® and Poly-L-(Lactic Acid) for Blown Film Application with Enhanced Mechanical Strength
Abstract
<jats:p>Mater-Bi® is one of the most commercialized starch-based blends used in biodegradable flexible packaging. However, the high ductility and low stiffness of Mater-Bi® might limit its application and developing a solution to tailor the stiffness and mechanical strength is highly desirable. In the present work, blends based on Mater-Bi® and poly-L-(lactic acid) (PLLA) at a different ratio from 70/30 to 50/50 wt% were prepared via melt-extrusion and the effect of the PLLA content and Joncryl ADR® as a reactive compatibilizing agent, on the mechanical properties, melts rheology, morphology and disintegration aptitude were investigated. The inclusion of PLLA in Mater-Bi® has a marked beneficial effect on the tensile strength and stiffness of the blend while maintaining acceptable ductility. The addition of the reactive compatibilizing agent contributed to improving the strength and elongation at the break of the blend. The melt rheology of the blend was also affected by the ratio of the two components, mostly when the Joncryl ADR® was present. The disintegration by biodegradation of the blend was preserved in the presence of PLLA, and it takes less than 30 days for the films to completely decompose and disintegrate under controlled composting conditions. Interestingly, a thin film from Mater-Bi®/PLLA 60/40 was successfully prepared by blown film extrusion, demonstrating a good balance between stretchability (elongation at break exceeding 100%) and stiffness (1.8 GPa). This work opened to broadening the use of starch-based biodegradable plastic toward more demanding applications such as mulching films.</jats:p>