People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Bikiaris, Dimitrios N.
Aristotle University of Thessaloniki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (71/71 displayed)
- 2024Novel Biobased Copolymers Based on Poly(butylene succinate) and Cutin: In Situ Synthesis and Structure Properties Investigationscitations
- 2024Influence of reactive diluent composition on properties and bio-based content of itaconic acid-based additive manufacturing materialscitations
- 2024Preparation and Structural-Thermodynamical Investigation of Renewable Copolyesters Based on Poly (Ethylene Succinate) and Polyisosorbidecitations
- 2024Thermal, Molecular Dynamics, and Mechanical Properties of Poly(Ethylene Furanoate)/Poly(ε-Caprolactone) Block Copolymers
- 2024Itaconic acid-based 3D printed nanocomposites: An in-depth study on the effect of nanoinclusions on the physicochemical properties and the printability of formulations based on polyester itaconatescitations
- 2024Biochar as a UV Stabilizer: Its Impact on the Photostability of Poly(butylene succinate) Biocompositescitations
- 2024Preparation and Characterisation of High-Density Polyethylene/Tannic Acid Composites
- 2024Melting Behavior of Compression Molded Poly(ester amide) from 2,5-Furandicarboxylic Acid
- 2024Valorization of Tomato Agricultural Waste for 3D-Printed Polymer Composites Based on Poly(lactic acid)citations
- 2023Particleboards with Recycled Material from Hemp-Based Panelscitations
- 2023Poly(Lactic Acid) Composites with Lignin and Nanolignin Synthesized by In Situ Reactive Processingcitations
- 2023Synthesis and Study of Fully Biodegradable Composites Based on Poly(butylene succinate) and Biocharcitations
- 2023Zirconia Nanoparticles as Reinforcing Agents for Contemporary Dental Luting Cements: Physicochemical Properties and Shear Bond Strength to Monolithic Zirconiacitations
- 2023Non-Isothermal Crystallization Kinetics of PBSu/Biochar Composites Studied by Isoconversional and Model Fitting Methodscitations
- 2022Poly(vinyl pyridine) and Its Quaternized Derivatives: Understanding Their Solvation and Solid State Propertiescitations
- 2022Poly(Glycerol Succinate) as Coating Material for 1393 Bioactive Glass Porous Scaffolds for Tissue Engineering Applicationscitations
- 2022Active Agents Incorporated in Polymeric Substrates to Enhance Antibacterial and Antioxidant Properties in Food Packaging Applicationscitations
- 2022Furanoate Polyesters/Polylactide/Reduced Graphene Oxide Nanocomposite Films: Thermomechanical and Gas Permeation Propertiescitations
- 2022Revisiting Non-Conventional Crystallinity-Induced Effects on Molecular Mobility in Sustainable Diblock Copolymers of Poly(propylene adipate) and Polylactidecitations
- 2022Incorporation of metal-based nanoadditives into the PLA matrixcitations
- 2022Effect of Micro- and Nano-Lignin on the Thermal, Mechanical, and Antioxidant Properties of Biobased PLA–Lignin Composite Filmscitations
- 2021Synthesis, Properties, and Enzymatic Hydrolysis of Poly(lactic acid)- co -Poly(propylene adipate) Block Copolymers Prepared by Reactive Extrusion
- 2021Incorporation of Metal-Based Nanoadditives into the PLA Matrix: Effect of Surface Properties on Antibacterial Activity and Mechanical Performance of PLA Nanoadditive Filmscitations
- 2021Synthesis and Characterization of Mesoporous Mg- and Sr-Doped Nanoparticles for Moxifloxacin Drug Delivery in Promising Tissue Engineering Applicationscitations
- 2021Synthesis and Characterization of Unsaturated Succinic Acid Biobased Polyester Resinscitations
- 2021Thermal Stability and Decomposition Mechanism of PLA Nanocomposites with Kraft Lignin and Tannincitations
- 2021Cold Crystallization Kinetics and Thermal Degradation of PLA Composites with Metal Oxide Nanofillerscitations
- 2021Multifunctionality of reduced graphene oxide in bioderived polylactide/poly(Dodecylene furanoate) nanocomposite filmscitations
- 2021Synthesis, Properties, and Enzymatic Hydrolysis of Poly(lactic acid)-co-Poly(propylene adipate) Block Copolymers Prepared by Reactive Extrusioncitations
- 2021Bottom-up development of nanoimprinted PLLA composite films with enhanced antibacterial properties for smart packaging applicationscitations
- 2019Paclitaxel Magnetic Core–Shell Nanoparticles Based on Poly(lactic acid) Semitelechelic Novel Block Copolymers for Combined Hyperthermia and Chemotherapy Treatment of Cancercitations
- 2019Enhancing the properties of poly(propylene succinate) by the incorporation of crystallizable symmetrical amido diolscitations
- 2019Sustainable thermoplastics from renewable resources:Thermal behavior of poly(1,4-cyclohexane dimethylene 2,5-furandicarboxylate)citations
- 2019Polyglycerol Hyperbranched Polyesters: Synthesis, Properties and Pharmaceutical and Biomedical Applicationscitations
- 2019Sustainable thermoplastics from renewable resourcescitations
- 2018Effect of surface functionalization of halloysite nanotubes on synthesis and thermal properties of poly(ε-caprolactone)citations
- 2018Sustainable Polymers from Renewable Resourcescitations
- 2018Sustainable Polymers from Renewable Resources:Polymer Blends of Furan-Based Polyesterscitations
- 2018Synthesis and characterization of in-situ-prepared nanocomposites based on poly(propylene 2,5-furan dicarboxylate) and aluminosilicate clayscitations
- 2018Design of a multifunctional nanoengineered PLLA surface by maximizing the synergies between biochemical and surface design sactericidal effectscitations
- 2018Synthesis and controlled crystallization of in situ prepared poly(butylene-2,6-naphthalate) nanocompositescitations
- 2018Enhanced thermal and fire retardancy properties of polypropylene reinforced with a hybrid graphene/glass-fibre fillercitations
- 2017Effect of MWCNTs and their modification on crystallization and thermal degradation of poly(butylene naphthalate)citations
- 2017Poly(ethylene furanoate-co-ethylene terephthalate) biobased copolymerscitations
- 2017Poly(ethylene furanoate-co-ethylene terephthalate) biobased copolymers:Synthesis, thermal properties and cocrystallization behaviorcitations
- 2016Mechanical, thermal and decomposition behavior of poly(epsilon-caprolactone) nanocomposites with clay-supported carbon nanotube hybridscitations
- 2016Fast Crystallization and Melting Behavior of a Long-Spaced Aliphatic Furandicarboxylate Biobased Polyester, Poly(dodecylene 2,5-furanoate)citations
- 2015Synthesis, properties and thermal behavior of poly(decylene-2,5-furanoate):A biobased polyester from 2,5-furan dicarboxylic acidcitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone)citations
- 2015β-Nucleated Polypropylene:Processing, Properties and Nanocompositescitations
- 2015Sustainable, eco-friendly polyesters synthesized from renewable resources:Preparation and thermal characteristics of poly(dimethyl-propylene furanoate)citations
- 2015Effect of graphene oxide and its modification on the microstructure, thermal properties and enzymatic hydrolysis of poly(ethylene succinate) nanocompositescitations
- 2015Furan-based polyesters from renewable resourcescitations
- 2015β-Nucleated Polypropylenecitations
- 2015Sustainable, eco-friendly polyesters synthesized from renewable resourcescitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone):Enhanced interfacial bonding and optimized mechanical propertiescitations
- 2015On the bio-based furanic polyesterscitations
- 2015Synthesis of the bio-based polyester poly(propylene 2,5-furan dicarboxylate). Comparison of thermal behavior and solid state structure with its terephthalate and naphthalate homologuescitations
- 2015Furan-based polyesters from renewable resources:Crystallization and thermal degradation behavior of poly(hexamethylene 2,5-furan-dicarboxylate)citations
- 2015Synthesis, properties and thermal behavior of poly(decylene-2,5-furanoate)citations
- 2015On the bio-based furanic polyesters:Synthesis and thermal behavior study of poly(octylene furanoate) using fast and temperature modulated scanning calorimetrycitations
- 2014Effect of clay structure and type of organomodifier on the thermal properties of poly(ethylene terephthalate) based nanocompositescitations
- 2014Effect of clay structure and type of organomodifier on the thermal properties of poly(ethylene terephthalate) based nanocompositescitations
- 2014Evaluation of polyesters from renewable resources as alternatives to the current fossil-based polymers. Phase transitions of poly(butylene 2,5-furan-dicarboxylate)citations
- 2014Effect of silica nanoparticles modification on the thermal, structural, and decomposition properties of a β-nucleated poly(propylene-co-ethylene) matrixcitations
- 2014Synergistic effect of functionalized silica nanoparticles and a β-nucleating agent for the improvement of the mechanical properties of a propylene/ethylene random copolymercitations
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubes:Mechanical, thermal and rheological propertiescitations
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubescitations
- 2014Effect of nanofiller's size and shape on the solid state microstructure and thermal properties of poly(butylene succinate) nanocompositescitations
- 2013Crystallization and melting of propylene-ethylene random copolymers. Homogeneous nucleation and β-nucleating agentscitations
- 2012Effect of crystalline structure of polypropylene random copolymers on mechanical properties and thermal degradation kineticscitations
Places of action
Organizations | Location | People |
---|
article
Effect of Micro- and Nano-Lignin on the Thermal, Mechanical, and Antioxidant Properties of Biobased PLA–Lignin Composite Films
Abstract
<jats:p>Bio-based poly(lactic acid) (PLA) composite films were produced using unmodified soda micro- or nano-lignin as a green filler at four different contents, between 0.5 wt% and 5 wt%. The PLA–lignin composite polymers were synthesized by solvent casting to prepare a masterbatch, followed by melt mixing. The composites were then converted into films, to evaluate the effect of lignin content and size on their physicochemical and mechanical properties. Differential scanning calorimetry (DSC), supported by polarized light microscopy (PLM), infrared spectroscopy (FTIR-ATR), X-ray diffraction (XRD), and transmission electron microscopy (TEM) were employed to investigate the PLA crystallization and the interactions with Lignin (L) and Nanolignin (NL). The presence of both fillers (L and NL) had a negligible effect on the glass transition temperature (chain diffusion). However, it resulted in suppression of the corresponding change in heat capacity. This was indicative of a partial immobilization of the PLA chains on the lignin entities, due to interfacial interactions, which was slightly stronger in the case of NL. Lignin was also found to facilitate crystallization, in terms of nucleation; whereas, this was not clear in the crystalline fraction. The addition of L and NL led to systematically larger crystallites compared with neat PLA, which, combined with the higher melting temperature, provided indications of a denser crystal structure in the composites. The mechanical, optical, antioxidant, and surface properties of the composite films were also investigated. The tensile strength and Young’s modulus were improved by the addition of L and especially NL. The UV-blocking and antioxidant properties of the composite films were also enhanced, especially at higher filler contents. Importantly, the PLA–NL composite films constantly outperformed their PLA–L counterparts, due to the finer dispersion of NL in the PLA matrix, as verified by the TEM micrographs. These results suggest that bio-based and biodegradable PLA films filled with L, and particularly NL, can be employed as competitive and green alternatives in the food packaging industry.</jats:p>