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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Delgado-Aguilar, Marc
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Development of P(3HB-co-3HHx) nanohydroxyapatite (nHA) composites for scaffolds manufacturing by means of fused deposition modelingcitations
- 2023Lignin-Containing Cellulose Nanofibrils from TEMPO-Mediated Oxidation of Date Palm Waste: Preparation, Characterization, and Reinforcing Potentialcitations
- 2023Response of Polypropylene Composites Reinforced with Natural Fibers: Impact Strength and Water-Uptake Behaviorscitations
- 2022Valorization ofkraft lignin from black liquor in the production of composite materials with poly(caprolactone) and natural stone groundwood fiberscitations
- 2022Processing Polymer Blends of Mater-Bi® and Poly-L-(Lactic Acid) for Blown Film Application with Enhanced Mechanical Strengthcitations
- 2020High-Yield Lignocellulosic Fibers from Date Palm Biomass as Reinforcement in Polypropylene Composites: Effect of Fiber Treatment on Composite Properties
- 2020Lignin/poly(butylene succinate) composites with antioxidant and antibacterial properties for potential biomedical applicationscitations
- 2020Effect of the Fiber Treatment on the Stiffness of Date Palm Fiber Reinforced PP Composites: Macro and Micromechanical Evaluation of the Young's Modulus
- 2017Sugarcane bagasse reinforced compositescitations
- 2016Tensile strength assessment of injection-molded high yield sugarcane bagasse-reinforced polypropylenecitations
- 2016Starch-based biopolymer reinforced with high yield fibers from sugarcane bagasse as a technical and environmentally friendly alternative to high density polyethylenecitations
- 2016Cellulose nanofibers modified with alkyl ketene dimer for oil absorbent aerogels
Places of action
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article
Valorization ofkraft lignin from black liquor in the production of composite materials with poly(caprolactone) and natural stone groundwood fibers
Abstract
The development of new materials is currently focused on replacing fossil-based plastics with sustainable materials. Obtaining new bioplastics that are biodegradable and of the greenest possible origin could be a great alternative for the future. However, there are some limitations—such as price, physical properties, and mechanical properties—of these bioplastics. In this sense, the present work aims to explore the potential of lignin present in black liquor from paper pulp production as the main component of a new plastic matrix. For this purpose, we have studied the simple recovery of this lignin using acid precipitation, its thermoplastification with glycerin as a plasticizing agent, the production of blends with poly(caprolactone) (PCL), and finally the development of biocomposite materials reinforcing the blend of thermoplastic lignin and PCL with stone groundwood fibers (SGW). The results obtained show that thermoplastic lignin alone cannot be used as a bioplastic. However, its combination with PCL provided a tensile strength of, e.g., 5.24 MPa in the case of a 50 wt.% blend. In addition, when studying the properties of the composite materials, it was found that the tensile strength of a blend with 20 wt.% PCL increased from 1.7 to 11.2 MPa with 40 wt.% SGW. Finally, it was proven that through these biocomposites it is possible to obtain a correct fiber–blend interface.