| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Piasecki, Adam
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Crystallization behavior and thermal properties of octa-phenyl-substituted silsesquioxane-modified polylactide (PLA)citations
- 2023Compatibility of Sustainable Mater-Bi/poly(ε-caprolactone)/cellulose Biocomposites as a Function of Filler Modificationcitations
- 2023Biocarbon-based sustainable reinforcing system for technical polymers. The structure-properties correlation between polycarbonate (PC) and polybutylene terephthalate (PBT)-based blends containing acrylonitrile-butadiene-styrene (ABS)citations
- 2022Tribological Behavior and Wear Mechanism of Ni-Nano TiO2 Composite Sintered Material at Room Temperature and 600 °Ccitations
- 2022Comprehensive Investigation of Stoichiometry–Structure–Performance Relationships in Flexible Polyurethane Foamscitations
- 2022Tribological Properties of Cu-MoS2-WS2-Ag-CNT Sintered Composite Materialscitations
- 2022Rotational molding of polylactide (PLA) composites filled with copper slag as a waste filler from metallurgical industrycitations
- 2019Hydrothermal synthesis of multifunctional TiO2-ZnO oxide systems with desired antibacterial and photocatalytic propertiescitations
Places of action
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article
Comprehensive Investigation of Stoichiometry–Structure–Performance Relationships in Flexible Polyurethane Foams
Abstract
<jats:p>Polyurethane (PU) foams are versatile materials with a broad application range. Their performance is driven by the stoichiometry of polymerization reaction, which has been investigated in several works. However, the analysis was often limited only to selected properties and compared samples differing in apparent density, significantly influencing their performance. In the bigger picture, there is still a lack of comprehensive studies dealing with the stoichiometry impact on PU foams’ performance. Herein, flexible PU foams with a similar apparent density but differing in the isocyanate index (IIso) (from 0.80 to 1.20) were prepared. The stoichiometry–structure–performance relationships were investigated considering cellular and chemical structure, as well as the static and dynamic mechanical properties, thermal stability, thermal insulation, and acoustic performance. For IIso of 1.00, the biggest cell diameters of 274 µm were noted, which was 21–25% higher compared to 0.80 and 1.20 values. Increasing IIso reduced open cell content from 83.1 to 22.4%, which, combined with stiffening of structure (rise of modulus from 63 to 2787 kPa) resulting from crosslinking, limited the sound suppression ability around five times. On the other hand, it significantly strengthened the material, increasing tensile and compressive strength 4 and 13 times, respectively. Changes in the foams’ performance were also induced by the glass transition temperature shift from 6.1 to 31.7 °C, resulting from a greater extent of urethane groups’ generation and additional isocyanate reactions. Generally, the presented work provides important insights into preparing flexible PU foams and could be very useful for the future development of these materials.</jats:p>