| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Klonos, Panagiotis
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Preparation and Structural-Thermodynamical Investigation of Renewable Copolyesters Based on Poly (Ethylene Succinate) and Polyisosorbidecitations
- 2022Poly(vinyl pyridine) and Its Quaternized Derivatives: Understanding Their Solvation and Solid State Propertiescitations
- 2022Effect of Micro- and Nano-Lignin on the Thermal, Mechanical, and Antioxidant Properties of Biobased PLA–Lignin Composite Filmscitations
- 2021Comparative study of crystallization, semicrystalline morphology, and molecular mobility in nanocomposites based on polylactide and various inclusions at low filler loadingscitations
- 2017Effects of hydration/dehydration on interfacial polymer fraction and dynamics in nanocomposites based on metal-oxides and physically adsorbed polymercitations
- 2016Structure-properties investigations in hydrophilic nanocomposites based on polyurethane/poly(2-hydroxyethyl methacrylate) semi-interpenetrating polymer networks and nanofiller densil for biomedical application
- 2016Morphology and molecular dynamics investigation of PDMS adsorbed on titania nanoparticles: Effects of polymer molecular weight
- 2014Evaluation of the formed interface in biodegradable poly(l-lactic acid)/graphene oxide nanocomposites and the effect of nanofillers on mechanical and thermal propertiescitations
Places of action
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article
Poly(vinyl pyridine) and Its Quaternized Derivatives: Understanding Their Solvation and Solid State Properties
Abstract
<jats:p>A series of N-methyl quaternized derivatives of poly(4-vinylpyridine) (PVP) were synthesized in high yields with different degrees of quaternization, obtained by varying the methyl iodide molar ratio and affording products with unexplored optical and solvation properties. The impact of quaternization on the physicochemical properties of the copolymers, and notably the solvation properties, was further studied. The structure of the synthesized polymers and the quaternization degrees were determined by infrared and nuclear magnetic spectroscopies, while their thermal characteristics were studied by differential scanning calorimetry and their thermal stability and degradation by thermogravimetric analysis (TG-DTA). Attention was given to their optical properties, where UV-Vis and diffuse reflectance spectroscopy (DRS) measurements were carried out. The optical band gap of the polymers was calculated and correlated with the degree of quaternization. The study was further orientated towards the solvation properties of the polymers in binary solvent mixtures that strongly depend on the degree of quaternization, enabling a better understanding of the key polymer (solute)-solvent interactions. The assessment of the underlying solvation phenomena was performed in a system of different ratios of DMSO/H2O and the solvatochromic indicator used was Reichardt’s dye. Solvent polarity parameters have a significant effect on the visible spectra of the nitrogen quaternization of PVP studied in this work and a detailed path towards this assessment is presented.</jats:p>