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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Platnieks, Oskars
Riga Technical University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2023Poly(Butylene Succinate) Hybrid Multi-Walled Carbon Nanotube/Iron Oxide Nanocomposites: Electromagnetic Shielding and Thermal Propertiescitations
- 2023Fully bio-based thermoset composites from UV curable prepregs: Vegetable oil acrylate impregnated hemp nanopapercitations
- 2023Multilayered Composites with Carbon Nanotubes for Electromagnetic Shielding Applicationcitations
- 2023Sustainable hemp-based bioplastics with tunable properties via reversible thermal crosslinking of cellulosecitations
- 2022Sustainable Wax Coatings Made from Pine Needle Extraction Waste for Nanopaper Hydrophobizationcitations
- 2022Understanding the Impact of Microcrystalline Cellulose Modification on Durability and Biodegradation of Highly Loaded Biocomposites for Woody Like Materials Applicationscitations
- 2022Data on FTIR, photo-DSC and dynamic DSC of triethylene glycol dimethacrylate and N-vinylpyrrolidone copolymerization in the presence of ionic liquidscitations
- 2022Comparison of Carbon-Nanoparticle-Filled Poly(Butylene Succinate-co-Adipate) Nanocomposites for Electromagnetic Applicationscitations
- 2022Hydrothermal Ageing Effect on Reinforcement Efficiency of Nanofibrillated Cellulose/Biobased Poly(butylene succinate) Compositescitations
- 2021Lignin and Xylan as Interface Engineering Additives for Improved Environmental Durability of Sustainable Cellulose Nanopaperscitations
- 2021Adding value to poly (butylene succinate) and nanofibrillated cellulose-based sustainable nanocomposites by applying masterbatch processcitations
- 2021Cellulose Nanocrystals vs. Cellulose Nanofibers: A Comparative Study of Reinforcing Effects in UV-Cured Vegetable Oil Nanocompositescitations
- 2020Biorefinery Approach for Aerogelscitations
- 2020Sustainable tetra pak recycled cellulose / Poly(Butylene succinate) based woody-like composites for a circular economycitations
- 2020Bio-based poly(butylene succinate)/microcrystalline cellulose/nanofibrillated cellulose-based sustainable polymer composites:Thermo-mechanical and biodegradation studiescitations
- 2020Bio-Based Poly(butylene succinate)/Microcrystalline Cellulose/Nanofibrillated Cellulose-Based Sustainable Polymer Composites: Thermo-Mechanical and Biodegradation Studiescitations
- 2020Bio-Based Poly(butylene succinate)/Microcrystalline Cellulose/Nanofibrillated Cellulose-Based Sustainable Polymer Composites: Thermo-Mechanical and Biodegradation Studiescitations
- 2019Highly loaded cellulose/poly (butylene succinate) sustainable composites for woody-like advanced materials applicationcitations
Places of action
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article
Hydrothermal Ageing Effect on Reinforcement Efficiency of Nanofibrillated Cellulose/Biobased Poly(butylene succinate) Composites
Abstract
<jats:p>Nanofibrillated cellulose (NFC) is a sustainable functional nanomaterial known for its high strength, stiffness, and biocompatibility. It has become a key building block for the next-generation of lightweight, advanced materials for applications such as consumer products, biomedical, energy storage, coatings, construction, and automotive. Tunable and predictable durability under environmental impact is required for high performance applications. Bio-based poly (butylene succinate) (PBS) composites containing up to 50% NFC content were designed and aged in distilled water or at high relative humidity (RH98%). PBS/NFC composites are characterized by up to 10-fold increased water absorption capacity and diffusivity and the data are correlated with model calculations. Aged samples exhibited decreased crystallinity and melting temperature. Incorporation of NFC into PBS showed up to a 2.6-fold enhancement of the elastic modulus, although accompanied by a loss of strength by 40% and 8-fold reduction in the strain at failure of maximally loaded composites. Hydrothermal ageing had almost no influence on the tensile characteristics of PBS; however, there were considerable degradation effects in PBS/NFC composites. Altered reinforcement efficiency is manifested through a 3.7-fold decreased effective elastic moduli of NFC determined by applying the Halpin–Tsai model and a proportional reduction of the storage moduli of composites. The adhesion efficiency in composites was reduced by hydrothermal ageing, as measured Puckanszky’s adhesion parameter for the strength, which decreased from 3 to 0.8. For the loss factor, Kubat’s adhesion parameter was increased by an order. PBS filled with 20 wt.% NFC is identified as the most efficient composition, for which negative environmental degradation effects are counterbalanced with the positive reinforcement effect. The PBS matrix can be used to protect the NFC network from water.</jats:p>