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| Naji, M. |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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Sover, Alexandru
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Publications (5/5 displayed)
- 2024Predictive Modeling of Mechanical Properties from Degraded Polyamide 12 Powder in Laser Powder Bed Fusion
- 2022Characterization of welding notch designs and the impact on mechanical properties of 3D-printed PLA parts joined by a 3D pen
- 2022Use of the 3-Level Idea Diagram Method to Identify Constructive Solutions for the Development of a Thermoforming Mouldcitations
- 2021Improving Fracture Toughness of Tetrafunctional Epoxy with Functionalized 2D Molybdenum Disulfide Nanosheetscitations
- 2021Abrasive Erosion Behavior of Some Plastic Parts Obtained by 3D Printingcitations
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article
Improving Fracture Toughness of Tetrafunctional Epoxy with Functionalized 2D Molybdenum Disulfide Nanosheets
Abstract
<jats:p>In this work, improved fracture toughness of tetra-functional epoxy polymer was obtained using two-dimensional (2H polytype) molybdenum disulfide (MoS2) nano-platelets as a filler. Simultaneous in-situ exfoliation and functionalization of MoS2 were achieved in the presence of cetyltrimethylammonium bromide (CTAB) via sonication. The aim was to improve the dispersion of MoS2 nanoplatelets in epoxy and enhance the interfacial interaction between nanoplatelets and epoxy matrix. Epoxy nanocomposites with CTAB functionalized MoS2 (f-MoS2) nanoplatelets, ranging in content from 0.1 wt% up to 1 wt%, were fabricated. Modified MoS2 improved the fracture properties (81%) of tetrafunctional epoxy nanocomposites. The flexural strength and compressive strength improved by 64% and 47%, respectively, with 0.25 wt% loading of f-MoS2 nanoplatelets compared to neat epoxy. The addition of f-MoS2 nanoplatelets enhanced the thermomechanical properties of epoxy. This work demonstrated the potential of organically modified MoS2 nanoplatelets for improving the fracture and thermal behavior of tetrafunctional epoxy nanocomposites.</jats:p>