| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Schick, Christoph
University of Rostock
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2022Bulk enthalpy of melting of Poly (l-lactic acid) (PLLA) determined by fast scanning chip calorimetry
- 2021Crystal Nucleation and Growth in Cross-Linked Poly(ε-caprolactone) (PCL)citations
- 2021Nucleation behaviour and microstructure of single Al-Si12 powder particles rapidly solidified in a fast scanning calorimetercitations
- 2020Stability of crystal nuclei of poly (butylene isophthalate) formed near the glass transition temperature
- 2019Differential fast scanning calorimetry as analytical tool for mimicking melting and solidification in additive manufacturing
- 2019The Effect of Backbone Rigidity on the Glass Transition of Polymers of Intrinsic Microporosity Probed by Fast Scanning Calorimetrycitations
- 2019Enthalpy relaxation of polyamide 11 of different morphology far below the glass transition temperature
- 2019Review of the quench sensitivity of aluminium alloys: analysis of the kinetics and nature of quench-induced precipitationcitations
- 2018Cold-crystallization of poly(butylene 2,6-naphthalate) following Ostwald's rule of stagescitations
- 2017Determination of the glass transition temperature of difficult samples by Flash DSC
- 2015Control of precipitation during heat treatments based on DSC experiments
- 2015Temperature dependency of nucleation efficiency of carbon nanotubes in PET and PBTcitations
- 2014Crystallization of poly(ε-caprolactone)/MWCNT composites: a combined SAXS/WAXS, electrical and thermal conductivity studycitations
- 2014Kinetics of nucleation and crystallization in poly(butylene succinate) nanocompositescitations
- 2013Competitive crystallization of a propylene/ethylene random copolymer filled with a β-nucleating agent and multi-walled carbon nanotubes. conventional and ultrafast DSC studycitations
Places of action
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article
Crystal Nucleation and Growth in Cross-Linked Poly(ε-caprolactone) (PCL)
Abstract
<jats:p>The crystal nucleation and overall crystallization kinetics of cross-linked poly(ε-caprolactone) was studied experimentally by fast scanning calorimetry in a wide temperature range. With an increasing degree of cross-linking, both the nucleation and crystallization half-times increase. Concurrently, the glass transition range shifts to higher temperatures. In contrast, the temperatures of the maximum nucleation and the overall crystallization rates remain the same, independent of the degree of cross-linking. The cold crystallization peak temperature generally increases as a function of heating rate, reaching an asymptotic value near the temperature of the maximum growth rate. A theoretical interpretation of these results is given in terms of classical nucleation theory. In addition, it is shown that the average distance between the nearest cross-links is smaller than the estimated lamellae thickness, which indicates the inclusion of cross-links in the crystalline phase of the polymer.</jats:p>