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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Espuche, Eliane
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (58/58 displayed)
- 2023Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocompositescitations
- 2023Effect of Amino-Functionalized Polyhedral Oligomeric Silsesquioxanes on Structure-Property Relationships of Thermostable Hybrid Cyanate Ester Resin Based Nanocompositescitations
- 2022Gas barrier properties of polylactide/cellulose nanocrystals nanocompositescitations
- 2022Tuning Polymer/TiO2 Nanocomposites Morphology by In Situ Non-Hydrolytic Sol-Gel Syntheses in Viscous Polymer Medium: Influence of the Polymer Nature and Oxygen Donorcitations
- 2021Multifunctional Pd-Based Nanocomposites with Designed Structure from In Situ Growth of Pd Nanoparticles and Polyether Block Amide Copolymercitations
- 2021Multifunctional Pd-Based Nanocomposites with Designed Structure from In Situ Growth of Pd Nanoparticles and Polyether Block Amide Copolymercitations
- 2021Influence of the Graphene Filler Nature on the Morphology and Properties of Melt Blended EVOH Based Nanocompositescitations
- 2021Thermally stable nanoporous cyanate ester resin/linear polyurethane hybrid networks created by nuclear technologiescitations
- 2019Numerical analysis of 3D mass diffusion in random (nano) composite systems: Effects of polydispersity and intercalation on barrier propertiescitations
- 2018Specific properties of in situ ruthenium-catalyzed polyamide 12/polydimethylsiloxane compatibilized blendcitations
- 20183D Mass diffusion in ordered nanocomposite systems: Finite element simulation and phenomenological modelingcitations
- 2016SiOx and SiOxCzHw mono- and multi-layer deposits for improved polymer oxygen and water vapor barrier propertiescitations
- 2016Polymer Nanocomposite Film with Metal Rich Surface Prepared by In Situ Single-Step Formation of Palladium Nanoparticles: An Interesting Way to Combine Specific Functional Propertiescitations
- 2016Preparation, characterization and barrier properties of silver/montmorillonite/starch nanocomposite filmscitations
- 2016Impact of coated calcium carbonate nanofillers and annealing treatments on the microstructure and gas barrier properties of poly(lactide) based nanocomposite filmscitations
- 2015Study of the influences of film processing conditions and glycerol amount on the water sorption and gas barrier properties of novel sodium caseinate filmscitations
- 2015Polypropylene/Layered Double Hydroxide Nanocomposites: Synergistic Effect of Designed Filler Modification and Compatibilizing Agent on the Morphology, Thermal, and Mechanical Propertiescitations
- 2015Influence of high spressures on CH4, CO2 and H2S solubility in polyethylene: Experimental and molecular simulation approaches for pure gas and gas mixtures. Modelling of the sorption isothermscitations
- 2015Starch/silver nanocomposite: Effect of thermal treatment temperature on the morphology, oxygen and water transport propertiescitations
- 2015Reinforcement of the Gas Barrier Properties of Polyethylene and Polyamide Through the Nanocomposite Approach: Key Factors and Limitationscitations
- 2015Effect of silver nanoparticles' generation routes on the morphology, oxygen, and water transport properties of starch nanocomposite filmscitations
- 2014Influence of montmorillonite and film processing conditions on the morphology of polyamide 6: Effect on ethanol and toluene barrier propertiescitations
- 2014Green synthesis of colloid silver nanoparticles and resulting biodegradable starch/silver nanocompositescitations
- 2014Synthesis and physical properties of new layered silicates based on ionic liquids: improvement of thermal stability, mechanical behaviour and water permeability of PBAT nanocompositescitations
- 2014Erasure of the processing effects in polyamide 6 based cast films by the introduction of montmorillonite: Effect on water and oxygen transport propertiescitations
- 2014Effect of different metal in situ growing routes on the morphology and gas separation properties of polyetherimide/palladium nanocomposite asymmetric membranescitations
- 2014Hybrid Films of Polyetherimide Containing In Situ Grown Ag, Pd, and AgPd Alloy Nanoparticles: Synthesis Route, Morphology, and Gas Transport Propertiescitations
- 2013Microstructure and properties of styrene-butadiene rubber based nanocomposites prepared from an aminosilane modified synthetic lamellar nanofillercitations
- 2013Polyelectrolyte/fluorinated polymer interpenetrating polymer networks as fuel cell membranecitations
- 2012Melt Mixing of a Styrene/Butadiene Copolymer with an Aqueous Slurry of Zirconium Phosphate as a Route for the Preparation of Nanocompositescitations
- 2012Physicochemical properties of organoclay filled polylactic acid/natural rubber blend bionanocompositescitations
- 2012PLA based nanocomposites : Influence of nanofiller shape, composition and surface treatment on the morphology and gas barrier properties
- 2012Surface modification of calcium carbonate nanofillers by fluoro- and alkyl-alkoxysilane: Consequences on the morphology, thermal stability and gas barrier properties of polyvinylidene fluoride nanocompositescitations
- 2012Modification of alpha-ZrP nanofillers by amines of different chain length: Consequences on the morphology and mechanical properties of styrene butadiene rubber based nanocompositescitations
- 2011Effect of an organo-modified montmorillonite on PLA crystallization and gas barrier propertiescitations
- 2011Synergism Effect of Montmorillonite and Cellulose Whiskers on the Mechanical and Barrier Properties of Natural Rubber Compositescitations
- 2011Control of the gas diffusion and interaction in nanocomposites: from high gas barrier materials to active membranes
- 2011Gas diffusion in nanocomposites: from high gas barrier materials to active membranes
- 2010Experimental and modelling studies of transport in starch nanocomposite films as affected by relative humiditycitations
- 2010Morphology and barrier properties of polylactide/nano-sized precipitated calcium carbonate: effect of the filler surface treatment
- 2010Experimental and modelling studies of transport in starch nanocomposites films as affected by relative humidity: water sorption and kinetics, oxygen permeability
- 2010Dielectric properties of polyamide 6-montmorillonite nanocompositescitations
- 2010Gas diffusion in nanocomposites based on polymers and impermeable lamellar nanofillers
- 2010Modification of a-ZrP lamellar nanofillers: consequences on the morphology and gas transport properties of rubber-based nanocomposites
- 2009Effect of plasticizer on the structure of biodagradable starch/clay nanocomposites: thermal, water sorption and oxygen barrier propertiescitations
- 2008Poly(caprolactone)/clay masterbatches prepared in supercritical CO2 as efficient clay delamination promoters in poly(styrene-co-acrylonitrile)citations
- 2008Poly(caprolactone)/clay masterbatches prepared in supercritical CO2 as efficient clay delamination promoters in poly(styrene-co-acrylonitrile)citations
- 2008Water transport properties of polyamide 6 based nanocomposites prepared by melt blending: on the importance of the clay dispersion state on the water transport properties at high water activity
- 2008Influence of the compatibilizer polarity and molar mass on the morphology and the gas barrier properties of polyethylene/clay nanocomposites
- 2008Influence of alpha-ZrP fillers and process conditions on the morphology and the gas barrier properties of filled PA6 films
- 2008Metal nanocomposite films prepared in situ from PVA and silver nitrate. Study of the nanostructuration process and morphology as a function of the in situ routes
- 2007Influence of the interlayer cations on the surface characteristics of montmorillonites. Consequences on the morphology and gas barrier properties of polyethylene/montmorillonites nanocomposites
- 2007Influence of the clay content and dispersion state on the barrier properties of nylon 6 - montmorillonite nanocomposite films prepared by melt blending
- 2007Thermoplastic nanocomposites: From interfacial interaction design and mixing process conditions to gas barrier properties
- 2007In situ generation of active nanoparticles in polymer films: control of the functional properties by the control of the nanocomposite film morphology
- 2007Barrier properties of nanoclay-based thermoplastic nanocomposite membranes: Influence of the clay content and dispersion/modelling
- 2007Structure and morphology of nanocomposite films prepared from polyvinyl alcohol and silver nitrate: influence of thermal treatment
- 2007Barrier properties of nylon 6-montmorillonite nanocomposite membranes prepared by melt blending : Influence of the clay content and dispersion state. Consequences on modelling
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document
Influence of the Graphene Filler Nature on the Morphology and Properties of Melt Blended EVOH Based Nanocomposites
Abstract
<jats:p>In this study, ethylene vinyl alcohol (EVOH) nanocomposites elaborated by melt blending with four different fillers were investigated. Two graphene and two graphite fillers displaying various shapes were selected. The morphology, microstructure, thermal, mechanical, and barrier properties of the nanocomposite films prepared for 2 wt% fillers were analyzed with the aim to establish structure–function properties relationships. The nanocomposites properties significantly depended on the nature of the incorporated filler. The nanocomposite film prepared with the expanded graphite filler exhibited the highest Young modulus value (E = 1430 MPa) and the best barrier properties. Indeed, barrier properties, rarely studied at high water activities, evidenced a significant improvement with a decrease of the water vapor permeability by a factor 1.8 and of the oxygen permeabilities by a factor close to 2, for a critical water activity higher than 0.95. An increase of the thermal stability was also evidenced for this nanocomposite. It was shown that for all studied nanocomposites, the properties could be related to the dispersion state of the fillers and the simultaneous increase of the crystallinity of the matrix. A specific equation was proposed to take into account these both parameters to accurately predict the nanocomposite barrier properties.</jats:p>