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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Khan, Naveed Ahmed
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024The potential of nanocomposites (patuletin-conjugated with gallic acid-coated zinc oxide) against free-living amoebae pathogenscitations
- 2023Antibacterial Properties of Ethacridine Lactate and Sulfmethoxazole Loaded Functionalized Graphene Oxide Nanocompositescitations
- 2023Cinnamic acid and lactobionic acid based nanoformulations as a potential antiamoebic therapeuticscitations
- 2023Applications of Polyaniline-Based Molybdenum Disulfide Nanoparticles against Brain-Eating Amoebaecitations
- 2021Metal Organic Frameworks Derived Sustainable Polyvinyl Alcohol/Starch Nanocomposite Films as Robust Materials for Packaging Applicationscitations
- 2021Zinc oxide nanoparticles conjugated with clinically-approved medicines as potential antibacterial moleculescitations
- 2016Gold Nanoparticle Conjugation Enhances the Antiacanthamoebic Effects of Chlorhexidinecitations
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article
Metal Organic Frameworks Derived Sustainable Polyvinyl Alcohol/Starch Nanocomposite Films as Robust Materials for Packaging Applications
Abstract
<jats:p>Bio-nanocomposites-based packaging materials have gained significance due to their prospective application in rising areas of packaged food. This research aims to fabricate biodegradable packaging films based upon polyvinyl alcohol (PVA) and starch integrated with metal-organic frameworks (MOFs) or organic additives. MOFs offer unique features in terms of surface area, mechanical strength, and chemical stability, which make them favourable for supporting materials used in fabricating polymer-based packaging materials. zeolitic imidazolate frameworks (ZIFs) are one of the potential candidates for this application due to their highly conductive network with a large surface area and high porosity. Present research illustrates a model system based on ZIF-67 (C8H10N4Co) bearing 2–10 wt.% loading in a matrix of PVA/starch blend with or without pyrolysis to probe the function of intermolecular interaction in molecular packing, tensile properties, and glass transition process. ZIF-67 nanoparticles were doped in a PVA/starch mixture, and films were fabricated using the solution casting method. It was discovered through scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR) that addition of ZIF-67 and pyrolyzed ZIF-67 changed and enhanced the thermal stability of the membrane. Moreover, 2–10 wt.% loading of ZIF-67 effected the thermal stability, owing to an interlayer aggregation of ZIF-67. The membranes containing pyrolyzed ZIF-67 showed mechanical strength in the order of 25 MPa in a moderate loading of pyrolyzed ZIF-67 (i.e., at 4 wt.%). The crystallinity enhanced by an increment in ZIF-67 loading. On the other hand, pyrolyzed ZIF-67 carbon became amorphous because of the inert environment and elevated temperature. The surface area also increased after the pyrolysis, which helped to increase the strength of the composite films.</jats:p>