| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Celli, Annamaria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2024Valorization of coffee silverskin by cascade extraction of valuable biomolecules: preparation of eco‐friendly composites as the ultimate stepcitations
- 2023From Biomass to Bio‐Based Polymers: Exploitation of Vanillic Acid for the Design of New Copolymers with Tunable Propertiescitations
- 2022A contribution to the circular economy concept: biocomposites based on fully valorized agro-industrial residues.
- 2021Bio-based furan-polyesters/graphene nanocomposites prepared by in situ polymerizationcitations
- 2020Polymorphism and Multiple Melting Behavior of Bio-Based Poly(propylene 2,5-furandicarboxylate)citations
- 2020Organo-modified LDH fillers endowing multi-functionality to bio-based poly(butylene succinate): An extended study from the laboratory to possible marketcitations
- 2020Eco-Conversion of Two Winery Lignocellulosic Wastes into Fillers for Biocomposites: Vine Shoots and Wine Pomacescitations
- 2019Outstanding chain-extension effect and high UV resistance of polybutylene succinate containing amino-acid-modified layered double hydroxidescitations
- 2019Olive Mill Wastewater Valorization in Multifunctional Biopolymer Composites for Antibacterial Packaging Applicationcitations
- 2018Bio-Based PA11/Graphene Nanocomposites Prepared by In Situ Polymerizationcitations
- 2018Composites for « white and green » solutions: Coupling UV resistance and chain extension effect from poly(butylene succinate) and layered double hydroxides compositescitations
- 2016Potential use of rice endosperm fibers as reinforcing material in biocomposites
- 2016Multicomponent reinforcing system for poly(butylene succinate): Composites containing poly(l-lactide) electrospun mats loaded with graphenecitations
- 2016Poly(butylene succinate) bionanocomposites: a novel bio-organo-modified layered double hydroxide for superior mechanical propertiescitations
- 2016Strategy to Modify the Crystallization Behavior of EVOH32 through Interactions with Low-Molecular-Weight Moleculescitations
- 2016Photodegradation of TiO2 composites based on polyesters.citations
- 2016Photodegradation of TiO2 composites based on polyesterscitations
- 2016Evaluation of the retting process as a pre-treatment of vegetable fibers for the preparation of high-performance polymer biocompositescitations
- 2015Use of ionic liquids based on phosphonium salts for preparing biocomposites by in situ polymerizationcitations
- 2014X-ray diffraction and rheology cross-study of polymer chain penetrating surfactant tethered layered double hydroxide resulting into intermixed structure with polypropylene, poly(butylene)succinate and poly(dimethyl)siloxane.citations
- 2014X-ray diffraction and rheology cross-study of polymer chain penetrating surfactant tethered layered double hydroxide resulting into intermixed structure with polypropylene, poly(butylene)succinate and poly(dimethyl)siloxanecitations
- 2014Poly(1,4-dimethylcyclohexane adipate) nanocomposites with organoclays modified with ionic liquid based on phosphonium salt
- 2013Poly(butylene succinate)/layered double hydroxide bionanocomposites: relationships between chemical structure of LDH anion, delamination strategy, and final propertiescitations
- 2013Poly(butylene succinate)/Layered Double Hydroxide Bio-Nanocomposites: Relationships between Chemical Structure of LDH Anion, Delamination Strategy and Final Properties
- 2012Photodegradation of aliphatic polyesters and their composites with TiO2
Places of action
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article
Bio-based furan-polyesters/graphene nanocomposites prepared by in situ polymerization
Abstract
In situ intercalative polymerization has been investigated as a strategic way to obtain poly(propylene 2,5-furandicarboxylate) (PPF) and poly(hexamethylene 2,5-furandicarboxylate) (PHF) nanocomposites with different graphene types and amounts. Graphene (G) has been dispersed in surfactant stabilized water suspensions. The loading range in composites was 0.25–0.75 wt %. For the highest composition, a different type of graphene (XT500) dispersed in 1,3 propanediol, containing a 6% of oxidized graphene and without surfactant has been also tested. The results showed that the amorphous PPF is able to crystallize during heating scan in DSC and graphene seems to affect such capability: G hinders the polymer chains in reaching an ordered state, showing even more depressed cold crystallization and melting. On the contrary, such hindering effect is absent with XT500, which rather induces the opposite. Concerning the thermal stability, no improvement has been induced by graphene, even if the onset degradation temperatures remain high for all the materials. A moderate enhancement in mechanical properties is observed in PPF composite with XT500, and especially in PHF composite, where a significative increase of 10–20% in storage modulus E’ is maintained in almost all the temperature range. Such an increase is also reflected in a slightly higher heat distortion temperature. These preliminary results can be useful in order to further address the field of application of furan-based polyesters; in particular, they could be promising as packaging materials.