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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Joseph, Paul
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Enhancing Fire Retardance of Styrenic Polymers Through a Ter-Polymerization Route
- 2024The Effects of Nitrogen-Containing Monomers on the Thermal Degradation and Combustion Attributes of Polystyrenes Chemically Modified with Phosphonate Groupscitations
- 2023Gaseous- and Condensed-Phase Activities of Some Reactive P- and N-Containing Fire Retardants in Polystyrenescitations
- 2023Separation and Characterization of Plastic Waste Packaging Contaminated with Food Residuescitations
- 2023A STUDY OF THE INFLUENCE OF THE CHEMICAL ENVIRONMENTS OF P‐ AND N‐CONTAINING GROUPS ON THE FIRE RETARDANCE OF POLYSTYRENE
- 2022Thermal Decomposition of Styrenic Polymers Modified with Covalently Bound P- and N-containing Groups: Analysis of the Gaseous-Phase Mechanism
- 2022Gaseous- and Condensed-Phase Activities of Some Reactive P- and N-Containing Fire Retardants in Polystyrenescitations
- 2022Thermal and calorimetric investigations of some phosphorus-modified chain growth polymers 2: Polystyrenecitations
- 2021Phosphorus-Nitrogen Synergism in Fire Retarding Styrenic Polymers: Some Preliminary Studies
- 2020A Kinetic Analysis of the Thermal Degradation Behaviours of Some Bio-Based Substratescitations
- 2019Passive Fire Protection of Wood Substrates using Starch-based Formulations
- 2019A Study of the Thermal Degradation and Combustion Characteristics of Some Materials Commonly Used in the Construction Sectorcitations
- 2018Thermal and Calorimetric Evaluations of Polyacrylonitrile Containing Covalently-Bound Phosphonate Groupscitations
- 2018Thermal Degradation and Fire Properties of Fungal Mycelium and Mycelium - Biomass Composite Materialscitations
- 2017Structural studies of thermally stable, combustion-resistant polymer compositescitations
- 2014A three-dimensional Mn3O4 network supported on a nitrogenated graphene electrocatalyst for efficient oxygen reduction reaction in alkaline mediacitations
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article
A Kinetic Analysis of the Thermal Degradation Behaviours of Some Bio-Based Substrates
Abstract
In the present paper, we report on a detailed study regarding the thermal degradation behaviours of some bio-sourced substrates. These were previously identified as the base materials in the formulations for fireproofing wood plaques through our investigations. The substrates included: β-cyclodextrin, dextran, potato starch, agar-agar, tamarind kernel powder and chitosan. For deducing the Arrhenius parameters from thermograms obtained through routine thermogravimetric analyses (TGA), we used the standard Flynn–Wall–Ozawa (FWO) method and employed an in-house developed proprietary software. In the former case, five different heating rates were used, whereas in the latter case, the data from one dynamic heating regime were utilized. Given that the FWO method is essentially based on a model-free approach that also makes use of multiple heating rates, it can be considered in the present context as superior to the one that is dependent on a single heating rate. It is also relevant to note here that the values of energy of activation (Ea) obtained in each case should only be considered as apparent values at best. Furthermore, some useful, but limited, correlations were identified between the Ea values and the relevant parameters obtained earlier by us from pyrolysis combustion flow calorimetry (PCFC).