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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Arrieta, Marina Patricia
Universidad Politécnica de Madrid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Bio-Based and Biodegradable Polymeric Materials for a Circular Economycitations
- 2023Study of Ethylene-Removing Materials Based on Eco-Friendly Composites with Nano-TiO2citations
- 2022Effects of Steam Heat and Dry Heat Sterilization Processes on 3D Printed Commercial Polymers Printed by Fused Deposition Modelingcitations
- 2020Organic and Inorganic PCL-Based Electrospun Fiberscitations
- 2020Functional properties of photo-crosslinkable biodegradable polyurethane nanocompositescitations
- 2018Effect of the addition of polyester-grafted-cellulose nanocrystals on the shape memory properties of biodegradable PLA/PCL bionanocomposites
- 2018Thermally-activated shape memory effect on biodegradable nanocomposites based on PLA/PCL blends reinforced with hydroxyapatitecitations
- 2016Processing of edible films based on nanoreinforced gelatinized starchcitations
- 2016Biodegradable electrospun bionanocomposite fibers based on plasticized PLA-PHB blends reinforced with cellulose nanocrystalscitations
- 2015Biodegradable nanocomposites based on poly(ester-urethane) and nanosized hydroxyapatite: Plastificant and reinforcement effectscitations
- 2015Microstructure, mechanical, and thermogravimetric characterization of cellulosic by-products obtained from biomass seedscitations
- 2015Effect of D-Limonene on the Stabilization of Poly (Lactic Acid)citations
- 2014PLA-PHB/cellulose based films: Mechanical, barrier and disintegration propertiescitations
- 2014Multifunctional PLA PHB/cellulose nanocrystal films: Processing, structural and thermal propertiescitations
- 2013Prediction of properties value in thermoplastic mixtures applying box equivalent model incompatibility in recycled polymer blends
Places of action
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article
Organic and Inorganic PCL-Based Electrospun Fibers
Abstract
© 2020 by the authors. ; In this work, different nanocomposite electrospun fiber mats were obtained based on poly(e-caprolactone) (PCL) and reinforced with both organic and inorganic nanoparticles. In particular, on one side, cellulose nanocrystals (CNC) were synthesized and functionalized by “grafting from” reaction, using their superficial OH– group to graft PCL chains. On the other side, commercial chitosan, graphene as organic, while silver, hydroxyapatite, and fumed silica nanoparticles were used as inorganic reinforcements. All the nanoparticles were added at 1 wt% with respect to the PCL polymeric matrix in order to compare the different behavior of the woven no-woven nanocomposite electrospun fibers with a fixed amount of both organic and inorganic nanoparticles. From the thermal point of view, no difference was found between the effect of the addition of organic or inorganic nanoparticles, with no significant variation in the Tg (glass transition temperature), Tm (melting temperature), and the degree of crystallinity, leading in all cases to high crystallinity electrospun mats. From the mechanical point of view, the highest values of Young modulus were obtained when graphene, CNC, and silver nanoparticles were added to the PCL electrospun fibers. Moreover, all the nanoparticles used, both organic and inorganic, increased the flexibility of the electrospun mats, increasing their elongation at break. ; This work was funded by MAT2017-88123-P and PCIN-2017-036 (MINEICO FEDER EU). ; Peer reviewed