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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Plyushch, Artyom
Vilnius University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Effect of Particle Size on the Origin of Electromechanical Response in BaTiO 3 /PDMS Nanogeneratorscitations
- 2023Multilayered Composites with Carbon Nanotubes for Electromagnetic Shielding Applicationcitations
- 2022Electrical Resistivity and Microwave Properties of Carbon Fiber Felt Compositescitations
- 2022Phosphate bonded CoFe<sub>2</sub>O<sub>4</sub>–BaTiO<sub>3</sub> layered structures: Dielectric relaxations and magnetoelectric couplingcitations
- 20210.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 Phosphate Composites: Dielectric and Ferroelectric Propertiescitations
- 2020Dielectric Relaxation in the Hybrid Epoxy/MWCNT/MnFe2O4 Compositescitations
- 2020The Phosphate-Based Composite Materials Filled with Nano-Sized BaTiO3 and Fe3O4: Toward the Unfired Multiferroic Materialscitations
- 2019Synergy Effects in Electromagnetic Properties of Phosphate Ceramics with Silicon Carbide Whiskers and Carbon Nanotubescitations
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article
Dielectric Relaxation in the Hybrid Epoxy/MWCNT/MnFe2O4 Composites
Abstract
<jats:p>The electrical properties of epoxy/MWCNT (multi-walled carbon nanotubes)/MnFe2O4 hybrid composites loaded with MWCNTs (below, 0.09 vol.%, and above, 0.58 vol.%, percolation threshold) and varying concentrations of MnFe2O4 up to 10 vol.% were studied in a wide frequency range (20 Hz–40 GHz) at different temperatures (20 K–500 K). At low frequencies, the dielectric permittivity and the electrical conductivity of composites with fixed amounts of MWCNT are strongly dependent on MnFe2O4 content. For MWCNT concentrations above the percolation threshold (i.e., 0.58 vol.%), the electrical conductivity highly decreases with the increase of the MnFe2O4 fraction. In contrast, for the epoxy/MWCNT just below the onset of electrical conductivity (0.09 vol.% of MWCNTs), there exists an optimal concentration of MnFe2O4 inclusions (i.e., 0.025 vol.%), leading to a dramatic increase of the electrical conductivity by three orders of magnitude. The electrical transport in composites is mainly governed by electron tunneling at lower temperatures (below 200 K), and it is highly impacted by the matrix conductivity at higher temperatures (above 400 K). The electrical properties were discussed in terms of the Maxwell–Wagner relaxation and distributions of relaxation times. A non-invasive platform based on dielectric relaxation spectroscopy was proposed for enhancing the synergetic effect coursed by using multiple nanoinclusions in polymer composites just below the percolation threshold.</jats:p>