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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mecerreyes, David
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024Piperazinium Poly(Ionic Liquid)s as Solid Electrolytes for Lithium Batteriescitations
- 2024Light-Based 3D Multi-Material Printing of Micro-Structured Bio-Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronics.
- 2024Light‐Based 3D Multi‐Material Printing of Micro‐Structured Bio‐Shaped, Conducting and Dry Adhesive Electrodes for Bioelectronicscitations
- 2023Dual redox-active porous polyimides as high performance and versatile electrode material for next-generation batteriescitations
- 2022Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectorscitations
- 2022Fast Visible-Light Photopolymerization in the Presence of Multiwalled Carbon Nanotubes: Toward 3D Printing Conducting Nanocompositescitations
- 2020Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytescitations
- 2020Tuning the properties of a UV-polymerized, cross-linked solid polymer electrolyte for lithium batteriescitations
- 2020Influence of the cyclic vs. linear carbonate segments in the properties and performance of CO2-sourced polymer electrolytes for lithium batteriescitations
- 2018Biodegradable Polycarbonate Iongels for Electrophysiology Measurements.
- 2018Three-Dimensional conductive scaffolds as neural prostheses based on carbon nanotubes and polypyrrolecitations
- 2018Mixing poly(ionic liquid)s and ionic liquids with different cyano anionscitations
- 2018New electroactive macromonomers and multi-responsive PEDOT graft copolymerscitations
- 2017Novel Lithium Battery Single-Ion Block Copolymer Electrolytes based on Poly(Ethylene Oxide) and Methacrylic Sulfonamide
- 2017New Families of Single-Ion Block Copolymer Electrolytes based on Poly(Ethylene Oxide) and Methacrylic Sulfonamide for Lithium Batteries
- 2017Effect of the fullerene in the properties of thin PEDOT/C60films obtained by co-electrodepositioncitations
- 2017Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquidscitations
- 2014Post-polymerization modification and organocatalysis using reactive statistical poly(ionic liquid)-based copolymerscitations
- 2013Polymeric ionic liquids with mixtures of counter-anions: a new straightforward strategy for designing pyrrolidinium-based CO2 separation membranescitations
- 2010Parylene nanocomposites using modified magnetic nanoparticlescitations
- 2007Structure and properties of a semifluorinated diblock copolymer modified epoxy blendcitations
- 2000Ring-Opening Polymerization of γ-bromo-ε-caprolactone : A novel route to functionalized aliphatic polyesterscitations
- 2000Ring-opening polymerization of 6-hydroxynon-8-enoic acid lactone : Novel biodegradable copolymers containing allyl pendent groups
- 2000First example of an unsymmetrical difunctional monomer polymerizable by two living/controlled methods
Places of action
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article
Tuning the properties of a UV-polymerized, cross-linked solid polymer electrolyte for lithium batteries
Abstract
<p>Lithium metal anodes have been pursued for decades as a way to significantly increase the energy density of lithium-ion batteries. However, safety risks caused by flammable liquid electrolytes and short circuits due to lithium dendrite formation during cell cycling have so far prevented the use of lithium metal in commercial batteries. Solid polymer electrolytes (SPEs) offer a potential solution if their mechanical properties and ionic conductivity can be simultaneously engineered. Here, we introduce a family of SPEs that are scalable and easy to prepare with a photopolymerization process, synthesized from amphiphilic acrylic polymer conetworks based on poly(ethylene glycol), 2-hydroxy-ethylacrylate, norbornyl acrylate, and either lithium bis (trifluoromethanesulfonyl) imide (LiTFSI) or a single-ion polymethacrylate as lithium-ion source. Several conetworks were synthesized and cycled, and their ionic conductivity, mechanical properties, and lithium transference number were characterized. A single-ion-conducting polymer electrolyte shows the best compromise between the different properties and extends the calendar life of the cell.</p>