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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bruns, Nico
Technical University of Darmstadt
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2023Rendering Polyurethane Hydrophilic for Efficient Cellulose Reinforcement in Melt‐Spun Nanocomposite Fiberscitations
- 2023Synthesis of artificial cells via biocatalytic polymerisation-induced self-assembly
- 2023Artificial cell synthesis using biocatalytic polymerization-induced self-assemblycitations
- 2022Donor–acceptor stenhouse adduct-polydimethylsiloxane-conjugates for enhanced photoswitching in bulk polymerscitations
- 2021Nano‐3D‐printed photochromic micro‐objectscitations
- 2021Infiltration of proteins in cholesteric cellulose structurescitations
- 2020Tuning the properties of a UV-polymerized, cross-linked solid polymer electrolyte for lithium batteriescitations
- 2020Tuning the Properties of a UV-Polymerized, Cross-Linked Solid Polymer Electrolyte for Lithium Batteriescitations
- 2018Self-reporting fiber-reinforced composites that mimic the ability of biological materials to sense and report damagecitations
- 2018DNA-coated functional oil dropletscitations
- 2017Visible light-responsive DASA-polymer conjugatescitations
- 2017Visible light-responsive DASA-polymer conjugatescitations
- 2017Controlling enzymatic polymerization from surfaces with switchable bioaffinitycitations
- 2017Structural behavior of cylindrical polystyrene-block-poly(ethylene-butylene)-block-polystyrene (SEBS) triblock copolymer containing MWCNTscitations
- 2016Protein cages and synthetic polymerscitations
- 2014Mechanical unfolding of a fluorescent protein enables self-reporting of damage in carbon-fibre-reinforced compositescitations
- 2014Mechanical unfolding of a fluorescent protein enables self-reporting of damage in carbon-fibre-reinforced compositescitations
- 2014A chaperonin as protein nanoreactor for atom-transfer radical polymerizationcitations
- 2014Polymeric particulates for subunit vaccine deliverycitations
- 2013Combining polymers with the functionality of proteinscitations
- 2013Combining Polymers with the Functionality of Proteins: New Concepts for Atom Transfer Radical Polymerization, Nanoreactors and Damage Self-reporting Materialscitations
- 2013Hemoglobin and red blood cells catalyze atom transfer radical polymerizationcitations
- 2012ATRPasescitations
- 2012Use of a novel initiator for synthesis of amino-end functionalized polystyrene (NH 2-PS) by atom transfer radical polymerizationcitations
- 2011Selective and responsive nanoreactorscitations
- 2011Horseradish peroxidase as a catalyst for atom transfer radical polymerizationcitations
- 2011Phase behavior of vesicle-forming block copolymers in aqueous solutionscitations
- 2011Self-reporting materialscitations
- 2006Optical biochemical sensor for determining hydroperoxides in nonpolar organic liquids as archetype for sensors consisting of amphiphilic conetworks as immobilisation matricescitations
Places of action
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article
Tuning the properties of a UV-polymerized, cross-linked solid polymer electrolyte for lithium batteries
Abstract
<p>Lithium metal anodes have been pursued for decades as a way to significantly increase the energy density of lithium-ion batteries. However, safety risks caused by flammable liquid electrolytes and short circuits due to lithium dendrite formation during cell cycling have so far prevented the use of lithium metal in commercial batteries. Solid polymer electrolytes (SPEs) offer a potential solution if their mechanical properties and ionic conductivity can be simultaneously engineered. Here, we introduce a family of SPEs that are scalable and easy to prepare with a photopolymerization process, synthesized from amphiphilic acrylic polymer conetworks based on poly(ethylene glycol), 2-hydroxy-ethylacrylate, norbornyl acrylate, and either lithium bis (trifluoromethanesulfonyl) imide (LiTFSI) or a single-ion polymethacrylate as lithium-ion source. Several conetworks were synthesized and cycled, and their ionic conductivity, mechanical properties, and lithium transference number were characterized. A single-ion-conducting polymer electrolyte shows the best compromise between the different properties and extends the calendar life of the cell.</p>